Determination of mass transfer resistances of fast reactions in three‐phase mechanically agitated slurry reactors

• Published in: AIChE journal Vol. 63; no. 1; pp. 273 - 282
• Main Authors: Stamatiou, Ilias K., Muller, Frans L.
• Format: Journal Article
• Language: English
• Published: New York American Institute of Chemical Engineers 01.01.2017
• Subjects: Agitation; Catalysts; Chemical engineering; Chemical reactions; Constraining; Mass transfer; Mathematical analysis; Methodology; reaction kinetics; reactor analysis; Reactors; Slurries; Slurry reactors
• ISSN: 0001-1541; 1547-5905
• DOI: 10.1002/aic.15540

A methodology for the determination of mass transfer resistances of fast reactions in three‐phase mechanically agitated slurry reactors under the reaction conditions is presented. The mass transfer resistances affect significantly the overall mass transfer rate, the design equation and consequently the scale up of the reactor. There is not established methodology to separate the mass transfer resistances under reaction conditions by changing catalyst loading and manipulating the process variables, pressure and agitation speed. This allows to avoid the use of different catalyst particles and give the chance to calculate the mass transfer resistances without caring about the type of catalyst. We calculate each mass transfer resistance under conditions which do not allow to neglect any of the resistances. It is shown that the level off of mass transfer rate which is developed in the plot of mass transfer rate against agitation speed plots is not enough to determine the limiting regime. The hydrogenation of styrene over Pd/C (5% catalyst content) is used as case study to demonstrate the methodology. © 2016 American Institute of Chemical Engineers AIChE J, 63: 273–282, 2017