Supported catalysts based on layered double hydroxides for catalytic oxidation and hydrogenation: general functionality and promising application prospects
Oxidation and hydrogenation catalysis plays a crucial role in the current chemical industry for the production of key chemicals and intermediates. Because of their easy separation and recyclability, supported catalysts are widely used in these two processes. Layered double hydroxides (LDHs) with the...
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| Published in | Chemical Society reviews Vol. 44; no. 15; pp. 5291 - 5319 |
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| Main Authors | , , , , |
| Format | Journal Article |
| Language | English |
| Published |
England
07.08.2015
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| Subjects | |
| Online Access | Get full text |
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| Summary: | Oxidation and hydrogenation catalysis plays a crucial role in the current chemical industry for the production of key chemicals and intermediates. Because of their easy separation and recyclability, supported catalysts are widely used in these two processes. Layered double hydroxides (LDHs) with the advantages of unique structure, composition diversity, high stability, ease of preparation and low cost have shown great potential in the design and synthesis of novel supported catalysts. This review summarizes the recent progress in supported catalysts by using LDHs as supports/precursors for catalytic oxidation and hydrogenation. Particularly, partial hydrogenation of acetylene, hydrogenation of dimethyl terephthalate, methanation, epoxidation of olefins, elimination of NO
x
and SO
x
emissions, and selective oxidation of biomass have been chosen as representative reactions in the petrochemical, fine chemicals, environmental protection and clean energy fields to highlight the potential application and the general functionality of LDH-based catalysts in catalytic oxidation and hydrogenation. Finally, we concisely discuss some of the scientific challenges and opportunities of supported catalysts based on LDH materials.
This review focuses on the recent progress in supported catalysts based on LDH for use in catalytic hydrogenation and oxidation. |
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| Bibliography: | Dr Junting Feng received her PhD in Chemical Engineering and Technology from the Beijing University of Chemical Technology (BUCT) in 2010 under the supervision of Prof. Dianqing Li, after which she joined the staff of BUCT. She was promoted to associate professor in 2012. From 2012 to 2013 she worked as a visiting scholar at the Cardiff Catalysis Institute with Prof. Graham J. Hutchings in the area of "Designing LDH supported bimetallic catalysts for selective oxidation reactions". Her current research field is design and synthesis of novel catalytic materials as well as heterogeneous catalysis for selective oxidation and hydrogenation. Yiyun Du is currently a PhD candidate who studies in Prof. Dianqing Li's research group in the State Key Laboratory of Chemical Resource Engineering, BUCT. She got her bachelor's degree in Applied Chemistry from BUCT in 2012. Currently, she is working on the synthesis, characterization and applications of novel inorganic multifunctional catalysts for oxidation. Yufei He is currently a PhD candidate under the supervision of Professor Dianqing Li in the State Key Laboratory of Chemical Resource Engineering, BUCT. He received his BS degree in Material Science and Technology from the Wuhan University of Technology (2010). As a visiting student, he studied in Cardiff University for one year under the guidance of Professor Graham J. Hutchings in 2014. His research interests include the design and synthesis of high-performance supported Pd-based catalysts and the research on the structure-property relationship. Professor Dianqing Li obtained his BS and MS degrees from the Beijing University of Chemical Technology (BUCT) in 1983 and 1988 and PhD from Tianjin University in 2001. From 1989 to 1998, he worked as a senior engineer in Liming Research Institute of Chemical Industry. After postdoctoral research from 2001 to 2003 in BUCT, he joined the staff of BUCT and became a full professor. His research interests focus on novel catalytic materials and materials chemistry, involving both fundamental research and industrial applications. He is currently a director of the Beijing Engineering Center for Hierarchical Catalysts. Yanan Liu is currently a PhD candidate under the supervision of Prof. Dianqing Li in the State Key Laboratory of Chemical Resource Engineering, BUCT, China. She received her bachelor's degree in Applied Chemistry from BUCT in 2013. Her current research interests include the synthesis, characterization and applications of noble metal-based catalysts for selective hydrogenation. ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
| ISSN: | 0306-0012 1460-4744 1460-4744 |
| DOI: | 10.1039/c5cs00268k |