Amorphous nanostructuring in potassium niobium silicate glasses by SANS and SHG: a new mechanism for second-order optical non-linearity of glasses
Potassium niobium silicate (KNS) glasses xK 2O xNb 2O 5(1−2 x)SiO 2 with x=0.167; 0.182; 0.200; 0.220 and 0.250 have been subjected to prolonged heat treatments in a wide temperature range above T g. As a result, glasses exhibiting liquid-type phase separation phenomena have been isolated. Moreover...
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Published in | Journal of non-crystalline solids Vol. 306; no. 3; pp. 238 - 248 |
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Main Authors | , , , , , , , , |
Format | Journal Article |
Language | English Russian |
Published |
Amsterdam
Elsevier B.V
01.09.2002
Elsevier |
Online Access | Get full text |
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Summary: | Potassium niobium silicate (KNS) glasses
xK
2O
xNb
2O
5(1−2
x)SiO
2 with
x=0.167; 0.182; 0.200; 0.220 and 0.250 have been subjected to prolonged heat treatments in a wide temperature range above
T
g. As a result, glasses exhibiting liquid-type phase separation phenomena have been isolated. Moreover for each glass composition, the temperature zones have been determined to produce transparent, opalescent or opaque materials which have been studied by X-ray diffraction (XRD), small-angle neutron scattering (SANS) and second harmonic generation (SHG) techniques. SANS data unambiguously point at nanostructuring of KNS glasses in the scale of 5–20 nm under appropriate heat treatments near
T
g. In contrast to initial KNS glasses, nanostructured glasses exhibit SHG activity. For earliest stages of phase separation SHG-active glasses are characterized by fully amorphous XRD patterns. Further development of phase separation in glasses with increasing of their opalescence leads to diminishing SHG, and subsequently partial crystallization takes place giving opaque materials. Since relative maximum of SHG efficiency corresponds to non-crystalline nanostructured glasses, such new transparent second-order non-linear media may be of both scientific and practical interest. With regard to non-crystalline structure of nano-inhomogeneities, SHG mechanism in the glasses is supposed to be due to a combination of third-order non-linearity with a spatial modulation of linear polarizability. |
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Bibliography: | ObjectType-Article-2 SourceType-Scholarly Journals-1 ObjectType-Feature-1 content type line 23 |
ISSN: | 0022-3093 1873-4812 |
DOI: | 10.1016/S0022-3093(02)01170-5 |