Orientation, interaction and laser assisted self-assembly of organic single-crystal micro-sheets in a nematic liquid crystal

• Published in: Soft matter Vol. 11; no. 38; pp. 7674 - 7679
• Main Authors: Rasna, M. V, Zuhail, K. P, Ramudu, U. V, Chandrasekar, R, Dontabhaktuni, J, Dhara, Surajit
• Format: Journal Article
• Language: English
• Published: England 01.01.2015
• Subjects: Assembly; Colloids; Lasers; Liquid crystals; Nematic; Orientation; Self assembly; Single crystals
• ISSN: 1744-683X; 1744-6848
• DOI: 10.1039/c5sm01991e

Colloidal self-assembly has been one of the major driving themes in material science to obtain functional and advanced optical materials with complex architecture. Most of the nematic colloids reported so far are based on the optically isotropic spherical microparticles. We study organic single crystal micro-sheets and investigate their orientation, interaction and directed assembly in a nematic liquid crystal. The micro-sheets induce planar surface anchoring of the liquid crystal. The elasticity mediated pair interaction of micro-sheets shows quadrupolar characteristics. The average orientation angle of the micro-sheets in a planar cell and the angle between two micro-sheets in a homeotropic cell are supported by the Landau-de Gennes Q-tensor modeling. The self-assembly of the micro-sheets is assisted by a laser tweezer to form larger two-dimensional structures which have the potential for application of colloids in photonics. In this paper we report first experimental study on the orientation, interaction and directed-assembly of single crystal micro-sheets in nematic liquid crystals.