From C(sp2)-H to C(sp3)-H: systematic studies on transition metal-catalyzed oxidative C-C formation

In this tutorial review, we will summarize our recent efforts in transition metal-catalyzed oxidative coupling via C-H functionalization of aromatic, benzylic and allylic C-H bonds. Related works from other laboratories will be cited where suitable, aiming to give the readers a flavor of this field....

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Published inChemical Society reviews Vol. 41; no. 17; pp. 5588 - 5598
Main Authors Li, Bi-Jie, Shi, Zhang-Jie
Format Journal Article
LanguageEnglish
Published England 06.08.2012
Subjects
carbon-hydrogen bond activation
catalytic activity
chemical bonding
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Summary:In this tutorial review, we will summarize our recent efforts in transition metal-catalyzed oxidative coupling via C-H functionalization of aromatic, benzylic and allylic C-H bonds. Related works from other laboratories will be cited where suitable, aiming to give the readers a flavor of this field. Special emphasis is placed on the reaction design and development. Our recent developments in transition metal-catalyzed oxidative coupling via C-H functionalization of aromatic, benzylic and allylic C-H bonds is summarized.
Bibliography:Bi-Jie Li was born in 1985 in Hubei, China. He received his BS degree from Peking University in 2007. He is currently a fifth-year graduate student with Professor Shi at Peking University. His current research interests focus on transition metal catalyzed C-H bond activation.
Dr Zhang-Jie Shi obtained his BS at East China Normal University in 1996, and PhD with Professor Sheng-Ming Ma in the Shanghai Institute of Organic Chemistry (SIOC) in 2001. After his postdoctoral work with Professor Gregory L. Verdine at Harvard University and Professor Chuan He at the University of Chicago, he joined the chemistry faculty of Peking University in 2004, where he was promoted to a full Professor in 2008. His current research interests focus on transition metal catalyzed functionalization of inert chemical bonds and small molecules.
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ISSN:0306-0012
1460-4744
1460-4744
DOI:10.1039/c2cs35096c