TGA application for optimising the accelerated aging conditions and predictions of thermal aging of rubber

Changes in the residual compression set, tensile strength and elongation at break, as well as the oxygen absorption and mass change, are evaluated during the thermal oxidation of butadiene-nitrile-based carbon black-filled rubber. Activation energies for the processes are determined. Using TGA, the...

Full description

Saved in:
Bibliographic Details
Published inPolymer testing Vol. 32; no. 2; pp. 197 - 201
Main Authors Bystritskaya, Elena V., Monakhova, Tatyana V., Ivanov, Victor B.
Format Journal Article
LanguageEnglish
Published Elsevier Ltd 01.04.2013
Subjects
Activation energy
Breaking
Carbon
Compressing
Elongation
Nitrile rubber
Rubber
Tensile strength
Thermal degradation
Thermogravimetric analysis
Thermooxidation
Thermooxidation
Thermogravimetric analysis
Nitrile rubber
Activation energy
Online AccessGet full text

Cover

More Information
Summary:Changes in the residual compression set, tensile strength and elongation at break, as well as the oxygen absorption and mass change, are evaluated during the thermal oxidation of butadiene-nitrile-based carbon black-filled rubber. Activation energies for the processes are determined. Using TGA, the activation energy of the first thermal degradation stage (87-88 kJ/mol) corresponded to the increase in compression set. The activation energy of the second stage (116-117 kJ/mol) corresponded to the decrease in the elongation at break and oxygen absorption. These correlations confirm that TGA can be used to predict the thermal stability of rubber.
Bibliography:ObjectType-Article-2
SourceType-Scholarly Journals-1
ObjectType-Feature-1
content type line 23
ISSN:0142-9418
1873-2348
DOI:10.1016/j.polymertesting.2012.10.013