High photocatalytic degradation activity of polyethylene containing polyacrylamide grafted TiO2

• Published in: Polymer degradation and stability Vol. 98; no. 9; pp. 1754 - 1761
• Main Authors: Liang, Wenyao, Luo, Ying, Song, Shuangshuang, Dong, Xianming, Yu, Xiaoyuan
• Format: Journal Article
• Language: English
• Published: Kidlington Elsevier Ltd 01.09.2013; Elsevier
• Subjects: Applied sciences; Composites; Degradation; Density; Exact sciences and technology; Forms of application and semi-finished materials; Grafting; Molecular weight; Nanocomposite film; Photocatalysis; Photocatalytic degradation; Polyacrylamide grafted TiO2; Polyacrylamides; Polyethylene; Polyethylenes; Polymer industry, paints, wood; Technology of polymers; Titanium dioxide; Photocatalytic degradation; Polyacrylamide grafted TiO2; Polyethylene; Nanocomposite film; Titanium IV Oxides; Photocatalysis; Mechanical properties; Experimental study; Polyacrylamide grafted TiO; Composite material; Tensile strength; Ultraviolet radiation; Low density ethylene polymer; Reaction mechanism; Photochemical stability; Artificial ageing; Acrylamide polymer; Olefin polymer; Nanocomposite; Catalyst activity; Photochemical degradation; Graft polymers
• ISSN: 0141-3910; 1873-2321
• DOI: 10.1016/j.polymdegradstab.2013.05.027

A novel photocatalytic polyacrylamide grafted TiO2 (PAM-g-TiO2) nanocomposite was prepared and embedded into a low density polyethylene (LDPE) plastic. Photocatalytic degradation of the LDPE/PAM-g-TiO2 composite film was carried out under ambient conditions under ultraviolet light irradiation. The properties of composite film were compared with those of the pure LDPE film by measuring the changes in weight loss, carbonyl index, molecular weight, tensile strength and elongation at break. PAM-g-TiO2 embedded LDPE showed highly enhanced photocatalytic degradation. Irradiating the LDPE/PAM-g-TiO2 composite film for 520 h under UV light reduced its weight by 39.85% and average molecular weight (Mw) by 94.60%, while that of pure LDPE film was only 1.03% and 69.59%, respectively. The addition of PAM-g-TiO2 brought about the good dispersion of TiO2 in LDPE matrix and improved the hydrophilicity of composite film, which were able to facilitate the degradation of LDPE. The photocatalytic degradation mechanism of the films is briefly discussed.