Performance of PAM/PEI gel system for water shut-off in high temperature reservoirs: Laboratory study

• Published in: Journal of applied polymer science Vol. 132; no. 17; pp. np - n/a
• Main Authors: ElKarsani, Khalid S. M., Al-Muntasheri, Ghaithan A., Sultan, Abdulla S., Hussein, Ibnelwaleed A.
• Format: Journal Article
• Language: English
• Published: Hoboken Blackwell Publishing Ltd 05.05.2015; Wiley Subscription Services, Inc
• Subjects: Ammonium chloride; cross-linking; Distilled water; Dynamic stability; Dynamical systems; Dynamics; Flooding tests; Foundry sands; Gelation; gels; High temperature; Limestone; Materials science; Oil fields; Permeability; Polyetherimides; Polyethyleneimine; Polymers; Reservoirs; Retarders; Rheological properties; Rheology; Saline water; Sandstone; Seawater; Sodium chloride; Thermal stability
• ISSN: 0021-8995; 1097-4628
• DOI: 10.1002/app.41869

ABSTRACT A polymer gel is one of the common remediate methods to either reduce or totally block excessive water production in oilfields. Some systems demonstrated an excellent performance in treating the problem like polyacrylamide tert‐butyl acrylate (PAtBA)/polyethylenimine (PEI). In this study, polyacrylamide (PAM) was introduced as a cheap alternative to PAtBA that can tolerate high salinity reservoirs. The thermal stability of the PAM/PEI polymeric gel in saline water was examined at 150°C (302F). Samples prepared in sea water showed better stability compared with distilled and field water. Dynamic rheology and core‐flooding experiments were used to evaluate the PAM / PEI gel system at high temperatures. NaCl and NH4Cl were evaluated as a possible retarders for delaying the gelation time in order to achieve a successful placement. NH4Cl was found to be more effective retarder. Core‐flooding tests were conducted in sandstone and carbonate cores. The subject polymer gel was injected at rates typical of those in field applications. The injectivity of PAM/PEI was tested in Berea sandstone cores with initial permeability of ∼45 mD. The post‐treatment of the system showed a permeability reduction of ∼94% for a period of two weeks. The injectivity in low permeability carbonate cores required more retardation compared with the injectivity in sandstone cores. The gel reduced the permeability to brine in Indiana limestone core by 99.8% for more than 5 months. Rheology of cured gel samples indicated that the gel strength needs about one day of curing in the core for the strength to stabilize. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015, 132, 41869.