Structural Characterization and Remarkable Axial Ligand Effect on the Nucleophilic Reactivity of a Nonheme Manganese(III)-Peroxo Complex
The dark side of the Mn: A manganese(III) complex bearing a 13-membered macrocyclic ligand (1, see picture) binds a peroxo ligand in a side-on η² fashion. The reactivity of 1 is influenced by the introduction of anionic ligands trans to the peroxo group. Electronic and structural changes upon trans-...
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Published in | Angewandte Chemie (International ed.) Vol. 48; no. 23; pp. 4150 - 4153 |
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Main Authors | , , , , , , |
Format | Journal Article |
Language | English |
Published |
Weinheim
Wiley-VCH Verlag
01.01.2009
WILEY‐VCH Verlag |
Subjects | |
Online Access | Get full text |
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Summary: | The dark side of the Mn: A manganese(III) complex bearing a 13-membered macrocyclic ligand (1, see picture) binds a peroxo ligand in a side-on η² fashion. The reactivity of 1 is influenced by the introduction of anionic ligands trans to the peroxo group. Electronic and structural changes upon trans-ligand binding explain the increased nucleophilicity of the resulting complexes 1-X. |
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Bibliography: | http://dx.doi.org/10.1002/anie.200900118 These authors contributed equally to this work. The research was supported by KOSEF/MEST through the CRI Program and the WCU project (R31‐2008‐000‐10010‐0) (to W.N.) and by CPU time provided by the National Service of Computational Chemistry Software (to S.P. de V.). ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
ISSN: | 1433-7851 1521-3773 |
DOI: | 10.1002/anie.200900118 |