Formation of a compact oxide layer on AZ91D magnesium alloy by microarc oxidation via addition of cerium chloride into the MAO electrolyte

• Published in: Journal of Coatings Technology and Research Vol. 8; no. 6; pp. 765 - 771
• Main Authors: Laleh, M., Kargar, Farzad, Sabour Rouhaghdam, A.
• Format: Journal Article
• Language: English
• Published: Boston Springer US 01.11.2011; Springer; American Coatings Association, Inc
• Subjects: Applied sciences; Cerium; Chemistry and Materials Science; Coatings; Coatings industry; Corrosion and anti-corrosives; Corrosion and Coatings; Electrolytes; Exact sciences and technology; Industrial Chemistry/Chemical Engineering; Magnesium alloys; Magnesium industry; Materials Science; Metals. Metallurgy; Nonmetallic coatings; Polymer Sciences; Production techniques; Specialty metals industry; Surface treatment; Surfaces and Interfaces; Thin Films; Tribology; Microarc oxidation; AZ91D magnesium alloy; Coating; CeCl; Corrosion; Cerium Chlorides; Oxide layer; Experimental study; Non metal coating; Corrosion resistance; Additive; Morphology; Magnesium alloy; Oxidation
• ISSN: 1547-0091; 1945-9645; 1935-3804
• DOI: 10.1007/s11998-011-9357-7

Magnesium and its alloys have been used in many industries, but they are reactive and require protection against aggressive environments. In this study, a compact and relatively pore-free oxide coating was formed on AZ91D magnesium alloy to improve its corrosion resistance by means of the microarc oxidation (MAO) process via the addition of CeCl 3 as an additive into the MAO electrolyte. Morphologies and compositions of the coatings were studied with scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS), respectively. It was found that with the addition of CeCl 3 into the MAO electrolyte, the obtained coating showed more uniform morphology compared with the coating produced in the CeCl 3 free electrolyte. EDS analysis confirmed the presence of cerium in the coating formed in the electrolyte with CeCl 3 . Polarization tests results showed that the corrosion current density of the coating formed in the CeCl 3 containing electrolyte was less than that of the coating formed in the electrolyte without CeCl 3 . Furthermore, electrochemical impedance spectroscopy (EIS) tests indicated that the coating formed in the electrolyte with the addition of CeCl 3 improved the corrosion resistance of the substrate significantly.