Robust synthesis of a composite phase of copper vanadium oxide with enhanced performance for durable aqueous Zn-ion batteries

• Published in: Nanotechnology reviews (Berlin) Vol. 11; no. 1; pp. 1633 - 1642
• Main Authors: Cheng, Haoyan, Li, Xuerong, Hu, Hao, Yuan, Tongtong, Zhou, Shiqian, Dai, Shuge, Zhang, Di, Pan, Kunming
• Format: Journal Article
• Language: English
• Published: Berlin De Gruyter 18.04.2022; Walter de Gruyter GmbH
• Subjects: aqueous Zn-ion batteries; Cathodes; Copper; Diffusion rate; Electrochemical analysis; Electrochemistry; Electrode materials; Energy storage; Engineering research; Kinetics; Laboratories; Materials science; Microscopy; Performance enhancement; Power sources; Ratios; Reagents; Rechargeable batteries; Redox reactions; Transition metals; Vanadate; Vanadates; Vanadium; Vanadium oxides; Vanadium pentoxide; vanadium-based cathodes; Zinc
• ISSN: 2191-9097; 2191-9089; 2191-9097
• DOI: 10.1515/ntrev-2022-0103

Rechargeable aqueous Zn-ion batteries (AZIBs) have attracted much interest as next-generation power sources due to their economical, safe, and capacity superiorities. However, the cathodes used in AZIBs always suffer from sluggish kinetics, inducing inadequate rate performance and poor cycle ability. Pre-intercalating transition metal element in the cathode materials offers an effective strategy for improving diffusion kinetics of Zn and thus the electrochemical activity. In this work, different proportions of Cu pre-intercalated V were synthesized to form a composite phase of Cu and VO O nanosheets through the hydrothermal method. The reversible redox reaction of Cu and Cu , accompanied by the phase changes of copper vanadate and zinc vanadate, contributes to an excellent battery performance. When the molar ratio between Cu precursor and commercial V in the reaction solution is 1:2, the obtained material presents an outstanding electrochemical performance with the initial discharge capacity of 332 mAh g at 0.2 A g . The enlarged lattice distance together with the high conductivity leads to a high Zn ions diffusion rate of 10  cm  s . Even after 1,000 cycles at a current density of 2 A g , the capacity attenuation is only 0.035% per cycle, exhibiting distinctive activities toward AZIBs.