Novel low cost hybrid extraction-distillation-reverse osmosis process for complete removal of N,N-dimethylformamide from industrial wastewater

• Published in: Process safety and environmental protection Vol. 130; pp. 317 - 325
• Main Authors: Dou, Pengjia, Song, Jianfeng, Zhao, Shuwei, Xu, Shanshan, Li, Xuemei, He, Tao
• Format: Journal Article
• Language: English
• Published: Rugby Elsevier B.V 01.10.2019; Elsevier Science Ltd
• Subjects: Chloroform; Degradability; Dimethylformamide; Distillation; Economic analysis; Economic conditions; Extractants; Extraction; Industrial effluents; Industrial wastes; Industrial wastewater; Kerosene; N,N-Dimethylformamide; Osmosis; Phase ratio; Reverse osmosis; Simulation; Solvents; Wastewater; Wastewater analysis; Wastewater treatment; Distillation; Economic analysis; Extraction; Reverse osmosis; Wastewater; N,N-Dimethylformamide
• ISSN: 0957-5820; 1744-3598
• DOI: 10.1016/j.psep.2019.08.025

•A novel process for the treatment of N,N-dimethylformamide (DMF) wastewater was proposed.•Chloroform was selected for the extraction of DMF in the wastewater.•Kerosene was used to extract the dissolved chloroform in the raffinate.•High purity DMF could be recovered and the water quality improved greatly after treatment.•Total annual cost of the novel process is significantly lower than conventional distillation. Toxic N,N-dimethylformamide (DMF) is extensively used as a versatile solvent in various processes and thus released in large quantities in many industrial effluents. Low degradability requires effective treatment of DMF wastewater. A novel process combining extraction, distillation, and reverse osmosis (RO) was proposed. After screening, chloroform was selected as the solvent for DMF extraction. The extraction process conditions, namely phase ratio and the number of counter-current theoretical stages were determined by calculation and batch simulation. Kerosene was then used for the extraction of the dissolved chloroform in the wastewater after DMF extraction. The distillation columns for the separation and recovery of DMF and extractants were designed by Aspen Plus. The simulation results showed that more than 99.8% of DMF could be recovered with a purity of 99%. The salinity of the wastewater was reduced to a much lower level through RO process, and the quality of the wastewater improved greatly. Economic analysis showed that a significant reduction of 72.74% in the total annual cost (TAC) can be obtained by using the proposed process.