Glucose–fructose isomerisation promoted by basic hybrid catalysts

• Published in: Catalysis today Vol. 195; no. 1; pp. 114 - 119
• Main Authors: Souza, Rodrigo O.L., Fabiano, Demian Patrick, Feche, Cyril, Rataboul, Franck, Cardoso, Dilson, Essayem, Nadine
• Format: Journal Article Conference Proceeding
• Language: English
• Published: Amsterdam Elsevier B.V 15.11.2012; Elsevier
• Subjects: adsorption; calorimetry; Calorimetry of CO2; Catalysis; catalysts; catalytic activity; Chemical Sciences; Chemistry; Colloidal state and disperse state; Environment and Society; Environmental Sciences; Exact sciences and technology; fructose; General and physical chemistry; glucose; Glucose isomerisation into fructose; Hybrid solid bases; isomerization; Porous materials; sieves; Solid bases; Surface physical chemistry; temperature; Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry; Glucose isomerisation into fructose; Solid bases; Hybrid solid bases; Calorimetry of CO2; Water; Binary compound; Basic site; Carbon dioxide; Selectivity; Glucose; High temperature; Porous material; Physisorption; Solid; Molecular sieve; Template; Synthesis; Carbonates; Pretreatment; Chemisorption; Catalytic reaction; Calorimetry of CO; Isomerization; Transition element compounds; Conversion; Base; Fructose; Mesoporosity; Zirconia; Heterogeneous catalysis; Adsorption; Calorimetry; Biorefinery; Catalyst
• ISSN: 0920-5861; 1873-4308
• DOI: 10.1016/j.cattod.2012.05.046

Mesoporous ordered molecular sieves of the M41S family, containing their organic template, are active and selective solid bases in glucose isomerisation into fructose in water at 100°C. These solids are active without thermal pre-treatment due to their resistant towards irreversible CO2 poisoning, demonstrated by calorimetry of CO2 adsorption. Their performances are correlated to the presence of a high number of weak basic sites intermediate between chemisorption and physisorption. [Display omitted] ► Basic hybrid molecular sieves isomerise selectively glucose into fructose in water. ► Their weak basicity is water and CO2 tolerant. ► CO2 resistance of the basic hybrid molecular sieves is demonstrated by calorimetry. ► Basic hybrid molecular sieves are more selective than strong mineral bases. As-synthesised mesoporous ordered molecular sieves of the M41S family, containing their organic template and used without any pretreatment, were shown to be efficient weak basic catalysts in glucose–fructose isomerisation in water at 100°C. Selectivities higher than 80% were obtained for glucose conversion higher than 20%. By comparison, NaOH catalysed glucose–fructose isomerisation operates at lower temperature, but the selectivity is shown to be more strongly dependent on the duration and on the temperature of the reaction. Interestingly, a more conventional inorganic stronger solid base, such as zirconia promoted with Cs, is less active and requires higher reaction temperature, 150°C, to isomerise glucose into fructose or a pretreatment at high temperature aimed to remove the strongly adsorbed carbonate species. The superiority of the hybrid organic bases compared to the inorganic stronger solid base is correlated to the presence of a high number of weak basic sites intermediate between chemisorption and physisorption, resistant towards irreversible CO2 poisoning. This is demonstrated by calorimetry of CO2 adsorption.