Electrodialytic soil remediation enhanced by low frequency pulse current – Overall chronopotentiometric measurement

• Published in: Chemosphere (Oxford) Vol. 90; no. 4; pp. 1520 - 1525
• Main Authors: Sun, Tian R., Ottosen, Lisbeth M., Mortensen, John
• Format: Journal Article
• Language: English
• Published: Kidlington Elsevier Ltd 01.01.2013; Elsevier
• Subjects: anion exchange; Applied sciences; cation exchange; cations; Chronopotentiometry; clay; Decontamination. Miscellaneous; Electrochemistry; Electrodialytic remediation; energy; Energy saving; Environmental Restoration and Remediation - methods; Exact sciences and technology; Metals, Heavy - analysis; Metals, Heavy - chemistry; Polarization; Pollution; Pulse current; soil; Soil - chemistry; Soil and sediments pollution; Soil Pollutants - analysis; Soil Pollutants - chemistry; soil remediation; transportation; Electrodialytic remediation; Polarization; Chronopotentiometry; Energy saving; Pulse current; Energy consumption; Pulsed current; Energy economy; Electroremediation; Soil pollution; Electrodialysis; Decontamination; Kinetics
• ISSN: 0045-6535; 1879-1298
• DOI: 10.1016/j.chemosphere.2012.08.038

[Display omitted] ► The pulse current could decrease the energy input during the EDR process. ► The detailed mechanism was given by chronopotentiometric study. ► The distribution of the energy consumption in EDR cells was demonstrated. ► The rate controlling step of EDR process was determined. ► Polarization of the membranes and clay particles were characterized. The effect of low frequency pulse current on decreasing the polarization and energy consumption during the process of electrodialytic soil remediation was investigated in the present work. The results indicated that the transportation of cations through the cation exchange membrane was the rate controlling step both in constant and pulse current experiments, thus responsible for the major energy consumption. After 180h, a decrease in both the initial ohmic resistance in each pulse cycle and the resistance caused by concentration polarization of the anion exchange membrane were seen in the pulse current experiment compared to the constant current experiment. At the cation exchange membrane, only the resistance caused by concentration polarization decreased. In the soil compartment, an average of +60mV overpotential caused by the polarization of the electric double layer of the clay particles was obtained from the Nernstian behavior simulation of the relaxation process, which was significantly lower than the ohmic voltage drop induced by pore fluid resistance. Therefore, the ohmic polarization was the major contributor to the energy consumption in the soil compartment and diminished by pulse current.