Stable (sila)difluoromethylboranes via C-F activation of fluoroform derivatives

Lithium 1,3-bis(2,6-diisopropylphenyl)-2,3-dihydro-1H-1,3,2-diazaborol-2-uide activates the C-F linkage of fluoroform (CF H) and the Ruppert-Prakash reagent (CF SiMe ) to provide difluoromethyl-substituted boranes as air-stable compounds.

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Bibliographic Details
Published inChemical communications (Cambridge, England) Vol. 53; no. 40; pp. 5546 - 5548
Main Authors Ito, Shigekazu, Kato, Naoto, Mikami, Koichi
Format Journal Article
LanguageEnglish
Published England 2017
Subjects
Activation
Boranes
Derivatives
Fluoroform
Linkages
Lithium
Reagents
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Summary:Lithium 1,3-bis(2,6-diisopropylphenyl)-2,3-dihydro-1H-1,3,2-diazaborol-2-uide activates the C-F linkage of fluoroform (CF H) and the Ruppert-Prakash reagent (CF SiMe ) to provide difluoromethyl-substituted boranes as air-stable compounds.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
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ISSN:1359-7345
1364-548X
DOI:10.1039/c7cc02327h