Transformation of Organostannanes Based on Photocleavage of C-Sn Bond via Single Electron Transfer Process

In this work, we developed a new method for the transformation of organostannanes via radical process. In this reaction, highly reactive carbon radical species can be efficiently generated through HBr-catalyzed photocleavage of C-Sn bond via single electron transfer process. Under aerobic conditions...

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Published inScientific reports Vol. 7; no. 1; pp. 16559 - 7
Main Authors Li, Han, Jin, Ruiwen, Li, Yawei, Ding, Aishun, Hao, Xinqi, Guo, Hao
Format Journal Article
LanguageEnglish
Published England Nature Publishing Group 29.11.2017
Nature Publishing Group UK
Subjects
Aerobic conditions
Carboxylic acids
Electron transfer
Electrons
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Summary:In this work, we developed a new method for the transformation of organostannanes via radical process. In this reaction, highly reactive carbon radical species can be efficiently generated through HBr-catalyzed photocleavage of C-Sn bond via single electron transfer process. Under aerobic conditions, the in situ formed primary/secondary alkyl radicals can be further highly selectively oxidized into carboxylic acids/ketones, respectively.
Bibliography:ObjectType-Article-1
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ISSN:2045-2322
2045-2322
DOI:10.1038/s41598-017-16806-3