Quasi-molecular fluorescence from graphene oxide

• Published in: Scientific reports Vol. 1; no. 1; p. 85
• Main Authors: Galande, Charudatta, Mohite, Aditya D, Naumov, Anton V, Gao, Wei, Ci, Lijie, Ajayan, Anakha, Gao, Hui, Srivastava, Anchal, Weisman, R Bruce, Ajayan, Pulickel M
• Format: Journal Article
• Language: English
• Published: England Nature Publishing Group 08.09.2011
• Subjects: Aromatic compounds; Carbon; CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; Condensed-matter physics; Fluorophores; Graphene; Optical materials and structures; Optical spectroscopy; Optics; pH effects; Photochemistry; Physics
• ISSN: 2045-2322; 2045-2322
• DOI: 10.1038/srep00085

Aqueous dispersions of graphene oxide (GO) have been found to emit a structured, strongly pH-dependent visible fluorescence. Based on experimental results and model computations, this is proposed to arise from quasi-molecular fluorophores, similar to polycyclic aromatic compounds, formed by the electronic coupling of carboxylic acid groups with nearby carbon atoms of graphene. Sharp and structured emission and excitation features resembling the spectra of molecular fluorophores are present near 500 nm in basic conditions. The GO emission reversibly broadens and red-shifts to ca. 680 nm in acidic conditions, while the excitation spectra remain very similar in shape and position, consistent with excited state protonation of the emitting species in acidic media. The sharp and structured emission and excitation features suggest that the effective fluorophore size in the GO samples is remarkably well defined.