Research progress of vanadium pentoxide photocatalytic materials

• Published in: RSC advances Vol. 13; no. 33; pp. 22945 - 22957
• Main Authors: Li, Yanlin, Chen, Shenghua, Duan, Wenyuan, Nan, Yanli, Ding, Donghai, Xiao, Guoqing
• Format: Journal Article
• Language: English
• Published: England Royal Society of Chemistry 26.07.2023; The Royal Society of Chemistry
• Subjects: Carrier recombination; Catalytic activity; Chemical energy; Chemical reactions; Chemistry; Clean energy; Doping; Energy gap; Energy utilization; Internal energy; Noble metals; Oxidation; Photocatalysis; Semiconductor materials; Solar energy conversion; Valence; Vanadium pentoxide
• ISSN: 2046-2069; 2046-2069
• DOI: 10.1039/d3ra03648k

Photocatalytic reactions convert solar energy into chemical energy through a clean and green reaction process. Photocatalytic technology based on semiconductor materials provides us with a new idea in energy utilization and environmental governance. It was found that vanadium pentoxide (V 2 O 5 ) has a narrow band gap, wide response range in the visible region, high oxygen density in the V 2 O 5 lattice, high oxidation state of V 5+ , small energy requirement, and superior catalytic activity in partial oxidation. Therefore, the utilization rate of sunlight and photocatalytic oxidation can be greatly improved using V 2 O 5 materials. However, the narrow band gap of V 2 O 5 also makes it easier for the photogenerated electrons and holes to recombine in the excited state, and the stored energy is instantly consumed by carrier recombination. Therefore, how to promote the carrier separation of V 2 O 5 and improve the photocatalytic efficiency are the key problems to be solved. Herein, several methods to improve the photocatalytic performance of V 2 O 5 are reviewed, including metallic ion doping, non-metallic ion doping, semiconductor recombination, and noble metal deposition. Finally, it is suggested that future research directions should focus on a variety of modification methods simultaneously to promote photocatalytic efficiency and lower the cost, which will enable V 2 O 5 to have a broad development prospect in the field of photocatalysis. Photocatalytic reactions convert solar energy into chemical energy through a clean and green reaction process.