Unraveling the effect of solvents on the excited state dynamics of C540A by experimental and theoretical study

• Published in: RSC advances Vol. 13; no. 8; pp. 4924 - 4931
• Main Authors: Ge, Jing, Zhang, Xue-Dong, Peng, Yue, Bai, Xi-Lin
• Format: Journal Article
• Language: English
• Published: England Royal Society of Chemistry 06.02.2023; The Royal Society of Chemistry
• Subjects: Absorption spectra; Charge transfer; Chemistry; Excitation; Organic materials; Photochemistry; Red shift; Solvents
• ISSN: 2046-2069; 2046-2069
• DOI: 10.1039/d3ra00259d

In this work, the excited-state dynamics including intramolecular charge transfer (ICT) and the redshift of C540A have been investigated in a series of solvents on the basis of the Kamlet-Taft solvatochromic parameters ( π *, α , β ) using femtosecond transient absorption spectra and systematic theoretical calculation. We demonstrate that the redshift of the emission peak has a linear relationship with the α and π * scales and the effect of the π * scale is slightly stronger than that of the α scale. Meanwhile, the ICT rates can be suggested as relevant to not only the α scale but also the π * scale. Additionally, C540A-AN has proved that the excited state molecules have a unique inactivation mechanism because of the dark feature of the S 1 (CT) state. The valuable mechanistic information gleaned from the excited-state dynamics by the experimental and theoretical study would facilitate the design of organic materials for prospective applications in photochemistry and photobiology. The excited-state dynamics including intramolecular charge transfer and the redshift of C540A in a series of solvents have been investigated using femtosecond transient absorption spectra and systematic theoretical calculation.