Theoretical modeling of electrochemical nucleation and growth of a single metal nanocluster on a nanoelectrode
Theory of the initial stages of electrochemical formation and growth of a single metal nanocluster on an indifferent nanoelectrode has been developed and analyzed. General theoretical time dependences of the current and nanocluster size have been presented for the case of diffusion controlled growth...
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Published in | RSC advances Vol. 1; no. 12; pp. 6979 - 6984 |
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Main Authors | , , |
Format | Journal Article |
Language | English |
Published |
England
Royal Society of Chemistry
14.02.2020
The Royal Society of Chemistry |
Subjects | |
Online Access | Get full text |
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Summary: | Theory of the initial stages of electrochemical formation and growth of a single metal nanocluster on an indifferent nanoelectrode has been developed and analyzed. General theoretical time dependences of the current and nanocluster size have been presented for the case of diffusion controlled growth at potentio- and galvanostatic deposition, and cyclic voltammetry.
The models of formation and growth of a single nanocluster on a nanoelectrode are presented for three basic electrochemical methods (cyclic voltammetry, potentiostatic and galvanostatic electrodeposition). |
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Bibliography: | ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
ISSN: | 2046-2069 2046-2069 |
DOI: | 10.1039/d0ra00608d |