Efficient synthesis of Pt-Co nanowires as cathode catalysts for proton exchange membrane fuel cells

• Published in: RSC advances Vol. 1; no. 11; pp. 6287 - 6296
• Main Authors: Liu, Zhikun, Yin, Yanhong, Yang, Daijun, Zhang, Cunman, Ming, Pingwen, Li, Bing, Yang, Shuting
• Format: Journal Article
• Language: English
• Published: England Royal Society of Chemistry 10.02.2020; The Royal Society of Chemistry
• Subjects: Accelerated tests; Alloying; Catalysts; Cathodes; Chemistry; Chromium; Cobalt; Diameters; Durability; Maximum power density; Morphology; Nanocrystals; Nanowires; Oxygen reduction reactions; Platinum; Proton exchange membrane fuel cells; Protons; Reducing agents
• ISSN: 2046-2069; 2046-2069
• DOI: 10.1039/d0ra00264j

A simple and efficient method was used to prepare highly active and durable carbon-supported ultrathin Pt-Co nanowires (NWs) as oxygen reduction reaction (ORR) catalysts for the cathode in a proton exchange membrane fuel cell (PEMFC). Chromium hexacarbonyl plays a significant role in making Pt and Co form an alloyed NW, which acts as both a reducing agent and a structure directing agent. The nanocrystal exhibits a uniform nanowire morphology with a diameter of 2 nm and a length of 30 nm. In half cell tests, the Pt-Co NWs/C catalyst has a mass activity of 291.4 mA mg Pt −1 , which is significantly better than commercial Pt/C catalysts with 85.5 mA mg Pt −1 . And after the accelerated durability test (ADT), Pt-Co NWs/C shows an electrochemically active surface area (ECSA) loss of 19.1% while the loss in the commercial catalyst is 41.8%. Also, the membrane electrode assembly (MEA) was prepared using Pt-Co NWs/C as the cathode catalyst, resulting in a maximum power density of 952 mW cm −2 , which is higher than that of Pt/C. These results indicate that the one-dimensional structure of the catalyst prepared herein is favorable to improve the activity and durability, and the application of the catalyst in the MEA is also realized. A simple and efficient method was used to prepare highly active and durable carbon-supported ultrathin Pt-Co nanowires (NWs) as oxygen reduction reaction (ORR) catalysts for the cathode in a proton exchange membrane fuel cell (PEMFC).