Removal of phosphate by aluminum oxide hydroxide

• Published in: Journal of colloid and interface science Vol. 257; no. 1; pp. 135 - 140
• Main Authors: Tanada, Seiki, Kabayama, Mineaki, Kawasaki, Naohito, Sakiyama, Toru, Nakamura, Takeo, Araki, Mamiko, Tamura, Takamichi
• Format: Journal Article
• Language: English
• Published: San Diego, CA Elsevier Inc 2003; Elsevier
• Subjects: Adsorption; Aluminum Hydroxide - chemistry; Aluminum Oxide - chemistry; Chemistry; Exact sciences and technology; General and physical chemistry; Phosphate; Phosphates - chemistry; Phosphates - pharmacokinetics; Removal; Seawater; Seawater - chemistry; Selectivity; Solid-liquid interface; Surface physical chemistry; X-Ray Diffraction; Removal; Selectivity; Adsorption; Phosphate; Seawater; Aluminium hydroxide; Aluminium oxide; Phosphates; Liquid solid interface; Liquid solid adsorption; Selective adsorption; Adsorption isotherm; Experimental study; pH; Kinetic parameter; Aqueous solution
• ISSN: 0021-9797; 1095-7103
• DOI: 10.1016/S0021-9797(02)00008-5

The development and manufacture of an adsorbent to remove phosphate ion for the prevention of eutrophication in lakes are very important. The characteristics of phosphate adsorption onto aluminum oxide hydroxide were investigated to estimate the adsorption isotherms, the rate of adsorption, and the selectivity of adsorption. Phosphate was easily adsorbed onto aluminum oxide hydroxide, because of the hydroxyl groups. The adsorption of phosphate onto aluminum oxide hydroxide was influenced by pH in solution: the amount adsorbed was greatest at pH 4, ranging with pH from 2 to 9. The optimum pH for phosphate removal by aluminum oxide hydroxide is 4. The selectivity of phosphate adsorption onto aluminum oxide hydroxide was evaluated based on the amount of phosphate ion adsorbed onto aluminum oxide hydroxide from several anion complex solutions. It is phosphate that aluminum oxide hydroxide can selectively adsorb. The selectivity of phosphate onto aluminum oxide hydroxide was about 7000 times that of chloride. This result indicated that the hydroxyl groups on aluminum oxide hydroxide have selective adsorptivity for phosphate and could be used for the removal of phosphate from seawater.