Manipulation of light transmission from stable magnetic microrods formed by the alignment of magnetic nanoparticles

• Published in: RSC advances Vol. 11; no. 4; pp. 239 - 2396
• Main Authors: Seo, Yoon Ji, Lee, Hyung Gyu, Yang, Jun Seok, Jeong, Hwanyeop, Han, Jeonghun, Kim, Ji-Hye, Koo, Hyung-Jun, Yoon, Hyunsik
• Format: Journal Article
• Language: English
• Published: England Royal Society of Chemistry 12.01.2021; The Royal Society of Chemistry
• Subjects: Alignment; Chemistry; Dispersants; Dispersion; Energy; Energy consumption; Energy dissipation; Iron oxides; Isopropanol; Light transmission; Light valves; Magnetic fields; Nanoparticles; Permanent magnets; Polyethylene glycol; Smart materials; Solar energy; Windows (apertures)
• ISSN: 2046-2069; 2046-2069
• DOI: 10.1039/d0ra09511g

Due to the increasing energy consumption, smart technologies have been considered to automatically control energy loss. Smart windows, which can use external signals to modulate their transparency, can regulate solar energy by reflecting excess energy and retaining the required energy in a building without using additional energy to cool or heat the interiors of the building. Although many technologies have been developed for smart windows, they still need to be economically optimised. Here, we propose a facile method to synthesise magnetic microrods from magnetic nanoparticles by alignment using a magnetic field. To maximise the transparency difference in the ON and OFF states, we controlled the nanoparticle concentration in a dispersion liquid, magnetic field application time, and viscosity of the dispersant. Interestingly, the magnetic microrods remained stable when we mixed short-chain polymers (polyethylene glycol) with a liquid dispersant (isopropyl alcohol). Furthermore, the Fe 2 O 3 microrods maintained their shape for more than a week, while the Fe 3 O 4 microrods clustered after a day because they became permanent magnets. The anisotropic features of the magnetic rods were used as a light valve to control the transparency of the smart window. Magnetic microrods were synthesised from magnetic nanoparticles by alignment using a magnetic field. The transparency difference was maximised and the anisotropic features of the rods were used as a light valve to control the transparency of a smart window.