Reuse of EAF Slag as Reinforcing Filler for Polypropylene Matrix Composites

• Published in: JOM (1989) Vol. 67; no. 6; pp. 1370 - 1378
• Main Authors: Cornacchia, G., Agnelli, S., Gelfi, M., Ramorino, G., Roberti, R.
• Format: Journal Article
• Language: English
• Published: New York Springer US 01.06.2015; Springer Nature B.V
• Subjects: Chemistry/Food Science; Composite materials; Cooling; Earth Sciences; Engineering; Environment; Furnaces; Heavy metals; Impact strength; Investigations; Mechanical properties; Mineralogy; Physics; Polymers; Polypropylene; Slag; Solid solutions; Spectrum analysis; Steel; Steel production; Studies; Charpy Impact Test; Impact Strength; Wustite; Steel Slag; Slag Sample
• ISSN: 1047-4838; 1543-1851
• DOI: 10.1007/s11837-015-1396-6

Electric-arc furnace (EAF) slag, the by-product of steel fabricated at the EAF, is in most cases still sent to dumps, with serious environmental consequences. This work shows an innovative, economically convenient application for EAF slag: its use as reinforcing filler for polypropylene. Composites based on polypropylene containing 10–40 wt.% of EAF slag particles were prepared by melt compounding followed by injection molding. A physical–chemical analysis of the EAF slag was performed to determine microstructural features and main component phases. Leaching tests demonstrated that, although EAF slag can release small amounts of toxic elements, such as heavy metals, incorporating such material into the polymeric matrix immobilizes the heavy metals inside that matrix. The mechanical characterization of the polymer-based composites was performed. Incorporating EAF slag particles raises the Young’s modulus and the tensile strength at yield, whereas elongation at break and the impact strength of the polymer-based composite are significantly reduced only when large amounts of filler are added, i.e., 30% or more.