Time-Resolved Grazing-Incidence Diffraction Studies of Thin Films Using an Imaging-Plate Camera and Focusing Monochromator

• Published in: Journal of synchrotron radiation Vol. 5; no. 2; pp. 107 - 111
• Main Authors: Foran, G. J., Gentle, I. R., Garrett, R. F., Creagh, D. C., Peng, J. B., Barnes, G. T.
• Format: Journal Article
• Language: English
• Published: 5 Abbey Square, Chester, Cheshire CH1 2HU, England International Union of Crystallography 01.03.1998
• ISSN: 1600-5775; 0909-0495; 1600-5775
• DOI: 10.1107/S0909049597018128

A multiple imaging-plate (IP) detector system and focusing monochromator have been developed and successfully applied to the time-resolved study of phase transitions in Langmuir-Blodgett (LB) films by grazing-incidence X-ray diffraction (GIXD). The first reported application of imaging plates to a GIXD study was carried out by our group and proved to be very successful in the determination of thin-film structure [Foran, Peng, Steitz, Barnes & Gentle (1996). Langmuir, 12, 774-777]. To extend the capabilities of this system, an IP camera was designed and built which can accommodate up to 13 IPs (40 x 20 cm) inside the vacuum chamber of the main diffractometer at the Australian Beamline at the Photon Factory. The camera allows the enclosed IPs to be successively exposed and stored inside the diffractometer for later scanning. The focusing monochromator employed in this technique combines fixed exit-beam height with sagittal focusing of the second crystal and delivers a gain in flux of >/=20 times when measured through a 0.1 x 0.1 mm aperture. The utility of the system incorporating the IP camera and the focusing monochromator has been demonstrated through the study of temperature-dependent phase transitions in LB films of metal fatty acids.