Poly[2]catenanes and Cyclic Oligo[2]catenanes Containing Alternating Topological and Covalent Bonds: Synthesis and Characterization

A copper poly[2]catenate with a degree of polymerization (DP) of 8–9 has been prepared by copolymerization of a large bifunctionalized catenate with a terephthalic acid derivative (see picture). The metal‐free poly[2]catenand was obtained by demetalation of the copper poly[2]catenate.

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Bibliographic Details
Published inChemistry : a European journal Vol. 5; no. 6; pp. 1841 - 1851
Main Authors Weidmann, Jean-Luc, Kern, Jean-Marc, Sauvage, Jean-Pierre, Muscat, Dirk, Mullins, Susan, Köhler, Werner, Rosenauer, Christine, Räder, Hans Joachim, Martin, Kai, Geerts, Yves
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 04.06.1999
WILEY‐VCH Verlag
Wiley
Subjects
Catenanes
Chemistry
Chemistry, Multidisciplinary
Copper
Physical Sciences
Polycondensations
Science & Technology
Structure elucidation
Supramolecular chemistry
POLYESTERS
catenanes
TEMPLATED SYNTHESIS
TOF MASS-SPECTROMETRY
MOLECULAR THREADS
INTERLOCKED MACROCYCLIC LIGANDS
CATENANDS
POLYMER ANALYTICS
POLYCATENANES
copper
SYSTEMS
POLYROTAXANES
structure elucidation
supramolecular chemistry
polycondensations
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Summary:A copper poly[2]catenate with a degree of polymerization (DP) of 8–9 has been prepared by copolymerization of a large bifunctionalized catenate with a terephthalic acid derivative (see picture). The metal‐free poly[2]catenand was obtained by demetalation of the copper poly[2]catenate.
Bibliography:istex:124E953DD3A60629328838E88CD49E63FFF9767D
ark:/67375/WNG-FCLB91B7-S
ArticleID:CHEM1841
ISSN:0947-6539
1521-3765
DOI:10.1002/(SICI)1521-3765(19990604)5:6<1841::AID-CHEM1841>3.0.CO;2-Q