Studies of the effect of pressure and hydrogen permeance on the ethanol steam reforming reaction with palladium- and silica-based membranes

• Published in: Journal of membrane science Vol. 396; pp. 119 - 127
• Main Authors: Lim, Hankwon, Gu, Yunfeng, Oyama, S. Ted
• Format: Journal Article
• Language: English
• Published: Amsterdam Elsevier B.V 01.04.2012; Elsevier
• Subjects: aluminum oxide; artificial membranes; Chemistry; Colloidal state and disperse state; Commercialization; ethanol; Ethanol steam reforming; Exact sciences and technology; General and physical chemistry; hydrogen; industrial applications; Membrane reactor; Membranes; PdCu membranes; Permeance; Porous materials; Selectivity; Silica–alumina membranes; steam; Membrane reactor; Silica–alumina membranes; Ethanol steam reforming; PdCu membranes; Permeance; Selectivity; Commercialization; Binary compound; Support; Hydrogen; Industrial application; Alcohol; Porous material; Silica; Composite material; Alkanol; Membrane; Platinoid; Silica-alumina membranes; Diameter; Aluminium oxide; Packed bed; Ethanol; Transition metal; Palladium; Conversion; Silicon oxides; Steam reforming; Alumina
• ISSN: 0376-7388; 1873-3123
• DOI: 10.1016/j.memsci.2012.01.004

The performance of membrane reactors fitted with silica-based and palladium-based membranes with hydrogen permeances of 10−8–10−6molm−2s−1Pa−1 was studied and it was found that permeance had a favorable effect in the performance of the reactors. The system studied was the ethanol steam reforming. The highest ethanol conversion enhancement of 44% compared to a packed-bed reactor was obtained in a membrane reactor fitted with the highest hydrogen permeance of 3.9×10−6molm−2s−1Pa−1. The necessary permeance for commercial operation is calculated to be 2.5×10−7molm−2s−1Pa−1. [Display omitted] ► A membrane reactor produced enhanced ethanol conversion over a packed-bed reactor. ► Both H2 permeance and selectivity had a favorable effect in membrane reactors. ► A Weisz's “window of reality” analysis gave the needed permeance for commercialization. ► The necessary H2 permeance was 2.5×10−7molm−2s−1Pa−1 with 1cm OD tubes. The effects of hydrogen permeance and selectivity in the performance of membrane reactors for the ethanol steam reforming (EtOHSR) were studied at 1–10atm and 623K. The studies were performed with Pd–Cu and SiO2–Al2O3 composite membranes prepared by depositing the permselective components onto porous alumina supports with intermediate layers. The hydrogen permeances of the membranes varied from 5.2×10−8 to 3.9×10−6molm−2s−1Pa−1 and the selectivity ranged from 200 to 1000 (H2/CO2) at 623K, which allowed a broad set of conditions to be probed. Comparison studies with packed-bed reactor (PBR) and membrane reactor (MR) operation showed that higher ethanol conversions and hydrogen molar flows were obtained in the MRs for all pressures studied. It was determined that both hydrogen permeance and selectivity had a favorable effect on the EtOHSR reaction, with the highest ethanol conversion enhancement of 44% and hydrogen molar flow enhancement of 69% obtained in a MR fitted with a membrane with the highest hydrogen permeance. A criterion for the required permeance for industrial applications is developed, which for 1cm diameter membrane tubes is 2.5×10−7molm−2s−1Pa−1.