Monolithic, Hierarchical Surface Reliefs by Holographic Photofluidization of Azopolymer Arrays: Direct Visualization of Polymeric Flows
Hierarchically ordered, monolithic surface reliefs have attracted a great deal of interest due to their applications in advanced photonics and interface sciences. While many impressive achievements in fabrication of such surface reliefs have been made over the last decade, all established methods ar...
Saved in:
Published in | Advanced functional materials Vol. 21; no. 23; pp. 4412 - 4422 |
---|---|
Main Authors | , , |
Format | Journal Article |
Language | English |
Published |
Weinheim
WILEY-VCH Verlag
06.12.2011
WILEY‐VCH Verlag |
Subjects | |
Online Access | Get full text |
Cover
Loading…
Summary: | Hierarchically ordered, monolithic surface reliefs have attracted a great deal of interest due to their applications in advanced photonics and interface sciences. While many impressive achievements in fabrication of such surface reliefs have been made over the last decade, all established methods are still restricted by a number of factors, such as limited control of structural features, inherently induced structural defects, impractically low throughput, and technical barriers caused by mechanical contact. Herein, a deterministic and scalable fabrication of hierarchically ordered, monolithic surface reliefs by holographic photofluidization of azopolymer line arrays is demonstrated. In particular, it is shown that the structural features of monolithic surface reliefs including shapes and modulation heights can be deterministically tunable by adjusting the polarization and irradiation time of the holographic interference pattern. Moreover, by a direct visualization of azopolymeric flow according to the light polarization, a long‐standing question about the origin of surface‐relief‐grating formation on azopolymer film is addressed in terms of polymeric flows. Finally, as proof of concept for the practical application of the obtained hierarchical surface reliefs, dependence of wetting properties on modulating height is demonstrated.
Directional photofluidization allows a facile fabrication of various large‐area, hierarchically ordered monolithic surface‐relief gratings (SRGs) with precisely controlled structural features. Furthermore, the use of a micrometer‐scale periodic line pattern rather than a flat thin film, which has been generally used in conventional SRG studies, provides a powerful way to quantify the direction of flows of azopolymer during SRG formation. |
---|---|
Bibliography: | ark:/67375/WNG-CDLGG5TQ-N istex:9B077B94541C873FAAD44E2A6A41854F16FF0FC2 ArticleID:ADFM201101203 Micro/NanoPhotonics Lab., Department of Mechanical Engineering, KAIST H.S.K. and S.L. contributed equally to this work ObjectType-Article-2 SourceType-Scholarly Journals-1 ObjectType-Feature-1 content type line 23 |
ISSN: | 1616-301X 1616-3028 1616-3028 |
DOI: | 10.1002/adfm.201101203 |