Photoinduced Reversible Solid-to-Liquid Transitions and Directional Photofluidization of Azobenzene-containing Polymers

• Published in: Chinese journal of polymer science Vol. 39; no. 10; pp. 1225 - 1234
• Main Authors: Liang, Shuo-Feng, Nie, Chen, Yan, Jie, Zhang, Qi-Jin, Wu, Si
• Format: Journal Article
• Language: English
• Published: Beijing Chinese Chemical Society and Institute of Chemistry, CAS 01.10.2021; Springer Nature B.V
• Subjects: Azo compounds; Azo polymers; Characterization and Evaluation of Materials; Chemistry; Chemistry and Materials Science; Condensed Matter Physics; Feature Article; Glass transition temperature; Industrial Chemistry/Chemical Engineering; Liquefaction; Polarized light; Polymer Sciences; Polymers; Solidification; Solids; Switches; Photoresponsive; Polymer; Photoisomerization; Photoliquefaction; Azobenzene
• ISSN: 0256-7679; 1439-6203
• DOI: 10.1007/s10118-021-2519-x

Photoinduced reversible liquefaction and solidification of polymers enable processing and healing of polymers with light. Some azobenzene-containing polymers (azopolymers) exhibit two types of photoinduced liquefaction properties: photoinduced reversible solid-to-liquid transition and directional photofluidization. For the first type, light switches the glass transition temperature ( T g ) values of azopolymers and induces reversible solid-to-liquid transitions. For the second type, polarized light guides solid azopolymers to flow along the polarization direction. Here, we compare the two types of photoliquefaction and discuss their mechanisms. Recent progresses and applications based on photoliquefaction of azopolymers are also highlighted.