Structural evolution of metatitanic acid and iron removal during hydrolysis of industrial TiOSO4 solution

• Published in: Scientific reports Vol. 13; no. 1; p. 8509
• Main Authors: Tian, Congxue, Ma, Guangqiang, Ge, Hongwei
• Format: Journal Article
• Language: English
• Published: London Nature Publishing Group 25.05.2023; Nature Publishing Group UK; Nature Portfolio
• Subjects: Acids; Energy consumption; Hydrolysis; Moisture content; Titanium dioxide; Water content
• ISSN: 2045-2322; 2045-2322
• DOI: 10.1038/s41598-023-35741-0

Abstract The ferrous ion content of metatitanic acid affected the whiteness, purity and applications of TiO 2 , controlled by the hydrolysis conditions and metatitanic acid structure. The structural evolution of metatitanic acid and ferrous ion removal was investigated by hydrolyzing the industrial TiOSO 4 solution. The hydrolysis degree was conformed to Boltzmann model with good fitting. TiO 2 content of metatitanic acid gradually increased as hydrolysis proceeding due to its stronger compact structure and weaker colloidal property, caused by the aggregation and adjustment of the precipitated particles. At lower TiOSO 4 concentration, the crystal size increased significantly, lattice strain decreased, and average particle size constantly adjusted and reduced. The micropores and mesopores were mainly formed by aggregating and stacking of primary agglomerate particles, bonded and filled with sulfate and hydroxyl. The ferrous ion content decreased linearly with the increase of TiO 2 content, and reducing moisture content of metatitanic acid was an effective way to reduce Fe content. This would save more water and energy consumption, help to improve the clean production level of TiO 2 .