Electrochemical characteristics of the reduced graphene oxide/carbon nanotube/polypyrrole composites for aqueous asymmetric supercapacitors

• Published in: Journal of power sources Vol. 272; pp. 970 - 978
• Main Authors: PENG, Yu-Jung, WU, Tzu-Ho, HSU, Chun-Tsung, LI, Shin-Ming, CHEN, Ming-Guan, HU, Chi-Chang
• Format: Journal Article
• Language: English
• Published: Amsterdam Elsevier 25.12.2014
• Subjects: Applied sciences; Asymmetry; Capacitors; Capacitors. Resistors. Filters; Electric potential; Electrical engineering. Electrical power engineering; Electrodes; Exact sciences and technology; Graphene; Materials; Polypyrroles; Stability; Supercapacitors; Various equipment and components; Reduced graphene oxide/carbon nanotube; Carbon black; Carbon nanotubes; Asymmetric supercapacitor; Nanostructure; Electrolytic capacitor; Aqueous electrolyte; Composite material; Electrochemical characteristic; Conducting polymers; Aqueous medium; Supercapacitor; Nanocomposite; Aqueous solution; Reduced graphene oxide; Pyrrole polymer; Polypyrrole
• ISSN: 0378-7753; 1873-2755
• DOI: 10.1016/j.jpowsour.2014.09.022

Polypyrrole (PPy) has been polymerized onto reduced graphene oxide/carbon nanotube (rGO/CNT) to form an rGO/CNT/PPy composite using the chemical oxidation method. The electrochemical characteristics of the above composite in various aqueous electrolytes are systematically compared for the asymmetric supercapacitor application. The electrochemical characteristics of rGO/CNT/PPy in the electrolytes containing K+ show improved reversibility and higher stability. Introducing XC-72 in preparing the electrode has been found to enhance the specific capacitance and the cycle stability of rGO/CNT/PPy. The charge storage stability of rGO/CNT/PPy + XC-72 in various potential windows has been evaluated through the potential bias stress test. An asymmetric supercapacitor (ASC) with a positive electrode of Mn sub(3)O sub(4) and a negative electrode of rGO/CNT/PPy + XC-72 is successfully demonstrated, which shows specific energy and power of 14. Wh kg super(-1) and 6.62 kW kg super(-1) with a cell voltage of 1.6 V. This ASC with a cell voltage of 1.6 V shows excellent charge-discharge cycle stability and ideal capacitive behavior in NaNO sub(3) even after the application of 3250 charge-discharge cycles.