Effects of organic components in cuttlebone on the morphological and mechanical properties of peroxide cross-linked cuttlebone/natural rubber composites

• Published in: RSC advances Vol. 12; no. 22; pp. 13557 - 13565
• Main Authors: Chongcharoenchaikul, Thitipat, Miyaji, Kosuke, Junkong, Preeyanuch, Poompradub, Sirilux, Ikeda, Yuko
• Format: Journal Article
• Language: English
• Published: England Royal Society of Chemistry 05.05.2022; The Royal Society of Chemistry
• Subjects: Chemistry; Composite materials; Crosslinking; Crystallites; Crystallization; Fillers; Mechanical properties; Morphology; Natural rubber; Photovoltaic cells; Rubber; Rubber layers; Stress-strain curves
• ISSN: 2046-2069; 2046-2069
• DOI: 10.1039/d2ra01885c

The clarification of the role of organic components in cuttlebone particles on the morphological and mechanical properties in terms of the strain-induced crystallization (SIC) of peroxide cross-linked cuttlebone/natural rubber (NR) composites was revealed for the first time in this study. The organic components in cuttlebone particles affected the increased bound rubber layers and the decreased rubber chain orientation due to the formation of interfacial interactions (filler-to-filler and/or filler-to-rubber interactions). During SIC, the presence of organic components in cuttlebone particles did not significantly affect the crystallinity index and crystallite size in cuttlebone/NR composites. The increased moduli in the stressstrain curve resulted from the presence of biofiller, SIC, and organic components in the cuttlebone. Therefore, the presence of organic components in biofiller is an important factor in improving the mechanical properties of green rubber composite materials. The role of organic components in cuttlebone particles on the morphological and mechanical properties in terms of the strain-induced crystallization of peroxide cross-linked cuttlebone/NR composites was revealed for the first time in this study.