Molar heat capacity and electrolytic conductivity of aqueous solutions of [Bmim][MeSO 4] and [Bmim][triflate]

• Published in: Thermochimica acta Vol. 496; no. 1; pp. 105 - 109
• Main Authors: Lin, Pei-Yin, Soriano, Allan N., Caparanga, Alvin R., Li, Meng-Hui
• Format: Journal Article
• Language: English
• Published: Oxford Elsevier B.V 10.12.2009; Elsevier
• Subjects: 1-Butyl-3-methylimidazolium methylsulfate; 1-Butyl-3-methylimidazolium trifluoromethanesulfonate; Chemistry; Electrolytic conductivity; Exact sciences and technology; General and physical chemistry; Molar heat capacity; Solution properties; Solutions; 1-Butyl-3-methylimidazolium trifluoromethanesulfonate; Electrolytic conductivity; Molar heat capacity; 1-Butyl-3-methylimidazolium methylsulfate; Thermal properties; Electrical properties; Ionic conductivity; Heat capacity; Excess parameter; Aqueous solution; Ionic liquid
• ISSN: 0040-6031; 1872-762X
• DOI: 10.1016/j.tca.2009.07.006

Here we report the new measurements of molar heat capacity, C P and electrolytic conductivity, σ for aqueous solutions of 1-butyl-3-methylimidazolium methylsulfate, [Bmim][MeSO 4] and 1-butyl-3-methylimidazolium trifluoromethanesulfonate, [Bmim][triflate]. Heat capacities were measured from 303.2 to 353.2 K with a differential scanning calorimeter. Electrolytic conductivities were measured from 293.2 to 353.2 K with a commercial conductivity meter. The estimated uncertainties of C P and σ measurements were ±2 and ±1%, respectively. The present measurements of C P and σ were presented as a function of temperature and composition. An excess molar heat capacity C P E expression using the Redlich–Kister equation for the temperature and composition dependence was used to represent the measured C P and a modified empirical equation was used to correlate the temperature and composition dependence of the measured σ of the studied systems. The applied correlations represent the C P and σ measurements satisfactorily. The C P and σ values presented in this work are, in general, of sufficient accuracy for most engineering-design calculations.