Efficient degradation of perfluorooctanoic acid by UV–Fenton process

• Published in: Chemical engineering journal (Lausanne, Switzerland : 1996) Vol. 184; pp. 156 - 162
• Main Authors: Tang, Heqing, Xiang, Qingqing, Lei, Min, Yan, Jingchun, Zhu, Lihua, Zou, Jing
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 01.03.2012
• Subjects: carboxylic acids; chemical engineering; decarboxylation; Defluorination; free radicals; Hydroxyl radicals; ions; Perfluorooctanoic acid; UV–Fenton; Hydroxyl radicals; Perfluorooctanoic acid; UV–Fenton; Defluorination
• ISSN: 1385-8947; 1873-3212
• DOI: 10.1016/j.cej.2012.01.020

The degradation and decarboxylation of PFOA in UV–Fenton system proceeds through two pathways: attacking from the generated OH radicals and decomposing originated from the electron transfer interactions between PFOA and the generated Fe3+ ions. [Display omitted] ► It was confirmed that hydroxyl radicals could decompose PFOA. ► An efficient UV–Fenton approach was proposed for the degradation of PFOA. ► The degradation intermediates of PFOA were short-chain PFCs and fluoride ions. ► A two-stage mechanism was proposed for the UV–Fenton degradation of PFOA. Decomposition of perfluorooctanoic acid (PFOA) was investigated in UV–Fenton systems. It was found that PFOA could be efficiently degraded in the UV–Fenton system, producing fluoride ions and short-chain perfluorinated carboxylic acids. The degradation of PFOA could be divided into two stages: Within reaction time of 1h, the added PFOA was rapidly degraded, resulting in a PFOA removal of 87.9% and a defluorination efficiency of 35.8%; Beyond 1h, the PFOA removal was slowly increased to more than 95% at reaction time of 5h, along with the defluorination efficiency of 53.2%. This corresponded to a two-stage mechanism for the PFOA degradation process in the UV–Fenton system. The fast defluorination and degradation of PFOA at the first stage was attributed to the generation of strong oxidizing OH radicals, which accelerated PFOA decarboxylation. At the second stage, H2O2 was completely consumed, and the defluorination was mainly due to the interactions between PFOA and Fe3+ ions.