Synthesis, Characterization, and NH3-SCR Catalytic Performance of Fe-Modified MCM-36 Intercalated with Various Pillars

• Published in: Molecules (Basel, Switzerland) Vol. 28; no. 13; p. 4960
• Main Authors: Szymaszek-Wawryca, Agnieszka, Díaz, Urbano, Samojeden, Bogdan, Motak, Monika
• Format: Journal Article
• Language: English
• Published: Basel MDPI AG 24.06.2023; MDPI
• Subjects: alumina; Aluminum oxide; Ammonia; Catalysts; DeNOx; Ferric oxide; Geographical distribution; High temperature; intercalation; iron; Iron oxides; Lewis acid; MCM-36; Metal oxides; Molecular structure; Morphology; MWW zeolites; Nitrogen; Nitrous oxide; Physical characteristics; Physicochemical properties; Selective catalytic reduction; Silica; Zeolites
• ISSN: 1420-3049; 1420-3049
• DOI: 10.3390/molecules28134960

Two series of MCM-36 zeolites intercalated with various pillars and modified with iron were synthesized, analyzed with respect to their physicochemical properties, and tested as catalysts for the NH3-SCR process. It was found that the characteristic MWW morphology of MCM-36 can be obtained successfully using silica, alumina, and iron oxide as pillars. Additionally, one-pot synthesis of the material with iron resulted in the incorporation of monomeric Fe3+ species into the framework positions. The results of catalytic tests revealed that the one-pot synthesized sample intercalated with silica and alumina was the most efficient catalyst of NO reduction, exhibiting ca. 100% activity at 250 °C. The outstanding performance of the material was attributed to the abundance of Lewis acid sites and the beneficial influence of alumina on the distribution of iron species in the zeolite. In contrast, the active centers originating from the Fe2O3 pillars improved the NO conversion in the high-temperature range. Nevertheless, the aggregated particles of the metal oxide limited the access of the reacting molecules to the inner structure of the catalyst, which affected the overall activity and promoted the formation of N2O above 300 °C.