Mechanical properties of graphene oxide–polyacrylamide composites before and after swelling in water

• Published in: Polymer bulletin (Berlin, Germany) Vol. 75; no. 4; pp. 1431 - 1439
• Main Authors: Evingür, Gülşen Akın, Pekcan, Önder
• Format: Journal Article
• Language: English
• Published: Berlin/Heidelberg Springer Berlin Heidelberg 01.04.2018; Springer Nature B.V
• Subjects: Biomedical engineering; Biomedical materials; Carbon; Characterization and Evaluation of Materials; Chemistry; Chemistry and Materials Science; Complex Fluids and Microfluidics; Composite materials; Copolymerization; Crosslinking; Drug delivery systems; Equilibrium; Free radicals; Graphene; Hydrogels; Interfacial bonding; Load; Mechanical properties; Microscopy; Nanocomposites; Organic Chemistry; Original Paper; Physical Chemistry; Polyacrylamide; Polymer Sciences; Polymerization; Shear modulus; Soft and Granular Matter; Temperature; Tensile strength; Tissue engineering; Elasticity; Acrylamide; Toughness; Graphene oxide; Swelling
• ISSN: 0170-0839; 1436-2449
• DOI: 10.1007/s00289-017-2101-4

Polyacrylamide (PAAm) hydrogels have been proposed for use as promising biomaterials in biomedical and tissue engineering but their poor mechanical and water-retention properties have hindered their development. Graphene oxide (GO), an excellent nanofiller, was added to PAAm to produce mechanically strong GO–PAAm composites. The free radical crosslinking copolymerization method was used with GO content varying in the range between 5 and 50 µl of GO. The mechanical properties of the GO–PAAm composites are measured by compressive test, revealing a decrease in the shear modulus and toughness of the composites above 8 µl of GO by increasing GO content.