Effect of Pt and Pd promoter on Ni supported catalysts—A TPR/TPO/TPD and microcalorimetry study

• Published in: Journal of catalysis Vol. 258; no. 2; pp. 366 - 377
• Main Authors: Tanksale, A., Beltramini, J.N., Dumesic, J.A., Lu, G.Q.
• Format: Journal Article
• Language: English
• Published: Amsterdam Elsevier Inc 10.09.2008; Elsevier; Elsevier BV
• Subjects: Bimetallic catalysts; Catalysis; Catalysts; Chemistry; Exact sciences and technology; Experiments; General and physical chemistry; Hydrogen; Microcalorimetry; Nanomaterials; Sorbitol reforming; Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry; TPD; TPR; Bimetallic catalysts; TPD; Sorbitol reforming; Microcalorimetry; TPR; Sorbitol; Binary compound; Reducibility; Hydrogen; Active site; Reforming; Liquid phase; Supported catalyst; Particle; Promoter; Chemical reduction; Oxidation; Catalyst support; Mixed catalyst; Binding; Rod; Alloys; Desorption; Heterogeneous catalysis; Transmission electron microscopy; Thermodynamic properties; Alumina; Heat of adsorption
• ISSN: 0021-9517; 1090-2694
• DOI: 10.1016/j.jcat.2008.06.024

The promoting effect of Pt and Pd in bimetallic Ni–Pt and Ni–Pd catalysts supported on alumina nano-fibre (Alnf) were tested for the liquid phase reforming of sorbitol to produce hydrogen. The mono- and bimetallic catalysts were studied by different characterisation techniques such as: temperature programmed reduction, oxidation, CO desorption, microcalorimetry, TEM and STEM/EDX. Although bimetallic catalysts have long been the subject of great interest because of their exceptional properties compared to the monometallic catalysts, the reason behind their improved activity is still a question of debate. Experimental evidence showed that the addition of both Pt and Pd—even in a very small fraction—to the Ni catalyst increases its reducibility significantly. The TEM and STEM/EDX analysis confirmed that Pt and Ni are present as alloys in nano-sized rod shaped particles. At the same time it was found that the CO differential heat of adsorption is appreciably lowered in the bimetallic catalysts. This is substantial because reducing the CO binding strength can avoid the poisoning of the active metal sites. As a result, we demonstrate that the rate of H 2 formation from sorbitol reforming was 3 to 5 times higher for bimetallic catalysts when compared to the monometallic catalysts.