Use of chiral auxiliaries in the asymmetric synthesis of biologically active compounds: A review

This review article describes the use of some of the most popular chiral auxiliaries in the asymmetric synthesis of biologically active compounds. Chiral auxiliaries derived from naturally occurring compounds, such as amino acids, carbohydrates, and terpenes, are considered essential tools for the c...

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Published inChirality (New York, N.Y.) Vol. 31; no. 10; pp. 776 - 812
Main Authors Diaz‐Muñoz, Gaspar, Miranda, Izabel Luzia, Sartori, Suélen Karine, Rezende, Daniele Cristina, Alves Nogueira Diaz, Marisa
Format Journal Article
LanguageEnglish
Published United States Wiley Subscription Services, Inc 01.10.2019
Subjects
Amino acids
Asymmetric synthesis
Asymmetry
Bioactive compounds
Biological activity
biologically active compounds
Carbohydrates
chiral auxiliaries
Corey's chiral auxiliary
Evans' oxazolidinones
Modularity
Synthesis
Terpenes
chiral auxiliaries
Corey's chiral auxiliary
Evans' oxazolidinones
asymmetric synthesis
biologically active compounds
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Abstract This review article describes the use of some of the most popular chiral auxiliaries in the asymmetric synthesis of biologically active compounds. Chiral auxiliaries derived from naturally occurring compounds, such as amino acids, carbohydrates, and terpenes, are considered essential tools for the construction of highly complex molecules. We highlight the auxiliaries of Evans, Corey, Yamada, Enders, Oppolzer, and Kunz, which led to remarkable progress in asymmetric synthesis in the last decades and continue to bring advances until the present day.
AbstractList This review article describes the use of some of the most popular chiral auxiliaries in the asymmetric synthesis of biologically active compounds. Chiral auxiliaries derived from naturally occurring compounds, such as amino acids, carbohydrates, and terpenes, are considered essential tools for the construction of highly complex molecules. We highlight the auxiliaries of Evans, Corey, Yamada, Enders, Oppolzer, and Kunz, which led to remarkable progress in asymmetric synthesis in the last decades and continue to bring advances until the present day.
Author Sartori, Suélen Karine
Diaz‐Muñoz, Gaspar
Alves Nogueira Diaz, Marisa
Rezende, Daniele Cristina
Miranda, Izabel Luzia
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  fullname: Diaz‐Muñoz, Gaspar
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  organization: Universidade Federal de Minas Gerais
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  givenname: Izabel Luzia
  surname: Miranda
  fullname: Miranda, Izabel Luzia
  organization: Universidade Federal de Minas Gerais
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  givenname: Suélen Karine
  surname: Sartori
  fullname: Sartori, Suélen Karine
  organization: Universidade Federal de Minas Gerais
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  givenname: Daniele Cristina
  surname: Rezende
  fullname: Rezende, Daniele Cristina
  organization: Universidade Federal de Minas Gerais
– sequence: 5
  givenname: Marisa
  orcidid: 0000-0002-3370-4149
  surname: Alves Nogueira Diaz
  fullname: Alves Nogueira Diaz, Marisa
  organization: Universidade Federal de Viçosa
BackLink https://www.ncbi.nlm.nih.gov/pubmed/31418934$$D View this record in MEDLINE/PubMed
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Keywords chiral auxiliaries
Corey's chiral auxiliary
Evans' oxazolidinones
asymmetric synthesis
biologically active compounds
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Snippet This review article describes the use of some of the most popular chiral auxiliaries in the asymmetric synthesis of biologically active compounds. Chiral...
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SubjectTerms Amino acids
Asymmetric synthesis
Asymmetry
Bioactive compounds
Biological activity
biologically active compounds
Carbohydrates
chiral auxiliaries
Corey's chiral auxiliary
Evans' oxazolidinones
Modularity
Synthesis
Terpenes
Title Use of chiral auxiliaries in the asymmetric synthesis of biologically active compounds: A review
URI https://onlinelibrary.wiley.com/doi/abs/10.1002%2Fchir.23103
https://www.ncbi.nlm.nih.gov/pubmed/31418934
https://www.proquest.com/docview/2302908405
https://search.proquest.com/docview/2275250185
Volume 31
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