A novel multi-electrochromic polymer based on selenophene and benzotriazole via electrochemical and chemical polymerization

• Published in: Journal of macromolecular science. Part A, Pure and applied chemistry Vol. 56; no. 3; pp. 197 - 205
• Main Authors: Demir, Fatma, Keles, Duygu, Karabag, Aliekber, Cirpan, Ali, Toppare, Levent
• Format: Journal Article
• Language: English
• Published: New York Taylor & Francis 04.03.2019; Marcel Dekker, Inc
• Subjects: Benzotriazole; chemical polymerization; Colorimetry; D-A type polymers; electrochemical polymerization; Electrochromism; FeCl3; Ferric chloride; Iron chlorides; Monomers; Morphology; Multi-electrochromic polymer; Optical properties; Organic chemistry; Oxidation; Polymerization; Polymers; selenophene
• ISSN: 1060-1325; 1520-5738
• DOI: 10.1080/10601325.2019.1565541

In this study, a novel donor-acceptor type monomer was designed based on selenophene and benzotriazole with a bulky pendant group and synthesized through Stille coupling reaction. The monomer was polymerized electrochemically by using cyclic voltammetry and also chemically by oxidation in the presence of FeCl 3 . Both polymers were then compared in terms of their optical properties, electrochemical and spectroelectrochemical behaviors, kinetic and colorimetric properties and surface morphologies. Independent of the polymerization method, both electrochemically (E-PSeBTz) and chemically polymerized (C-PSeBTz) coatings showed quite similar properties. Both polymers have p-doping character and multichromic properties in their oxidized states. The polymers can be fully switched between their oxidized and neutral states in fairly short times with acceptable optical contrast at different wavelengths. Both polymers exhibit a λ max of 505 nm and the optical band gaps of the materials were found to be 1.85 eV and 1.80 eV for E-PSeBTz and C-PSeBTz, respectively.