Site-selective Suzuki-Miyaura coupling of heteroaryl halides - understanding the trends for pharmaceutically important classes

Suzuki-Miyaura cross-coupling reactions of heteroaryl polyhalides with aryl boronates are surveyed. Drawing on data from literature sources as well as bespoke searches of Pfizer's global chemistry RKB and CAS Scifinder® databases, the factors that determine the site-selectivity of these reactio...

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Published inChemical science (Cambridge) Vol. 8; no. 1; pp. 40 - 62
Main Authors Almond-Thynne, Joshua, Blakemore, David C, Pryde, David C, Spivey, Alan C
Format Journal Article
LanguageEnglish
Published England 01.01.2017
Subjects
Aromatic compounds
Chemical reactions
Coupling
Halides
Searching
Trends
Online AccessGet full text

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Abstract Suzuki-Miyaura cross-coupling reactions of heteroaryl polyhalides with aryl boronates are surveyed. Drawing on data from literature sources as well as bespoke searches of Pfizer's global chemistry RKB and CAS Scifinder® databases, the factors that determine the site-selectivity of these reactions are discussed with a view to rationalising the trends found.
AbstractList Suzuki-Miyaura cross-coupling reactions of heteroaryl polyhalides with aryl boronates are surveyed. Drawing on data from literature sources as well as bespoke searches of Pfizer's global chemistry RKB and CAS Scifinder registered databases, the factors that determine the site-selectivity of these reactions are discussed with a view to rationalising the trends found.
Suzuki-Miyaura cross-coupling reactions of heteroaryl polyhalides with aryl boronates are surveyed. Drawing on data from literature sources as well as bespoke searches of Pfizer's global chemistry RKB and CAS Scifinder® databases, the factors that determine the site-selectivity of these reactions are discussed with a view to rationalising the trends found.Suzuki-Miyaura cross-coupling reactions of heteroaryl polyhalides with aryl boronates are surveyed. Drawing on data from literature sources as well as bespoke searches of Pfizer's global chemistry RKB and CAS Scifinder® databases, the factors that determine the site-selectivity of these reactions are discussed with a view to rationalising the trends found.
Suzuki-Miyaura cross-coupling reactions of heteroaryl polyhalides with aryl boronates are surveyed. Drawing on data from literature sources as well as bespoke searches of Pfizer's global chemistry RKB and CAS Scifinder® databases, the factors that determine the site-selectivity of these reactions are discussed with a view to rationalising the trends found.
Author Blakemore, David C
Almond-Thynne, Joshua
Pryde, David C
Spivey, Alan C
Author_xml – sequence: 1
  givenname: Joshua
  surname: Almond-Thynne
  fullname: Almond-Thynne, Joshua
  email: a.c.spivey@imperial.ac.uk
  organization: Department of Chemistry , Imperial College London , South Kensington Campus , London , SW& 2AZ , UK . Email: a.c.spivey@imperial.ac.uk
– sequence: 2
  givenname: David C
  surname: Blakemore
  fullname: Blakemore, David C
  organization: Pfizer Worldwide Medicinal Chemistry , The Portway Building, Granta Park, Great Abington , Cambridge , CB21 6GS , UK
– sequence: 3
  givenname: David C
  surname: Pryde
  fullname: Pryde, David C
  organization: Pfizer Worldwide Medicinal Chemistry , The Portway Building, Granta Park, Great Abington , Cambridge , CB21 6GS , UK
– sequence: 4
  givenname: Alan C
  surname: Spivey
  fullname: Spivey, Alan C
  email: a.c.spivey@imperial.ac.uk
  organization: Department of Chemistry , Imperial College London , South Kensington Campus , London , SW& 2AZ , UK . Email: a.c.spivey@imperial.ac.uk
BackLink https://www.ncbi.nlm.nih.gov/pubmed/28451148$$D View this record in MEDLINE/PubMed
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Snippet Suzuki-Miyaura cross-coupling reactions of heteroaryl polyhalides with aryl boronates are surveyed. Drawing on data from literature sources as well as bespoke...
Suzuki–Miyaura cross-coupling reactions of heteroaryl polyhalides with aryl boronates are surveyed. Drawing on data from literature sources as well as bespoke...
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SubjectTerms Aromatic compounds
Chemical reactions
Coupling
Halides
Searching
Trends
Title Site-selective Suzuki-Miyaura coupling of heteroaryl halides - understanding the trends for pharmaceutically important classes
URI https://www.ncbi.nlm.nih.gov/pubmed/28451148
https://search.proquest.com/docview/1880025003
https://www.proquest.com/docview/1893546964
Volume 8
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