High gas storage capacities and stepwise adsorption in a UiO type metal-organic framework incorporating Lewis basic bipyridyl sites
A UiO type MOF with Lewis basic bipyridyl sites was synthesized and structurally characterized. After being activated by Soxhlet-extraction, this MOF exhibits high storage capacities for H2, CH4 and CO2, and shows unusual stepwise adsorption for liquid CO2 and solvents, indicating a sequential filli...
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Published in | Chemical communications (Cambridge, England) Vol. 50; no. 18; pp. 2304 - 2307 |
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Main Authors | , , , , , , |
Format | Journal Article |
Language | English |
Published |
England
01.01.2014
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Subjects | |
Online Access | Get full text |
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Summary: | A UiO type MOF with Lewis basic bipyridyl sites was synthesized and structurally characterized. After being activated by Soxhlet-extraction, this MOF exhibits high storage capacities for H2, CH4 and CO2, and shows unusual stepwise adsorption for liquid CO2 and solvents, indicating a sequential filling mechanism on different adsorption sites. |
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Bibliography: | ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
ISSN: | 1359-7345 1364-548X |
DOI: | 10.1039/c3cc48275h |