A novel 1,8-naphthalimide derivative with an open space for an anion: unique fluorescence behaviour depending on the binding anion's electrophilic properties

We have designed a novel 1,8-naphthalimide derivative with an open space for an anion. Computational calculation has predicted that the space could trap various anion species and photo-induced charge transfer depending on the anion's electrophilic properties. Indeed, the fluorescence behaviour...

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Bibliographic Details
Published inChemical communications (Cambridge, England) Vol. 51; no. 41; pp. 8596 - 8599
Main Authors Izawa, Hironori, Nishino, Shoji, Sumita, Masato, Akamatsu, Masaaki, Morihashi, Kenji, Ifuku, Shinsuke, Morimoto, Minoru, Saimoto, Hiroyuki
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 21.05.2015
Subjects
Anions
Anions - chemical synthesis
Anions - chemistry
Binding
Binding Sites
Charge transfer
Chemistry
Chemistry, Multidisciplinary
Computation
Derivatives
Fluorescence
Mathematical analysis
Molecular Structure
Naphthalimides - chemistry
Open spaces
Physical Sciences
Quantum Theory
Science & Technology
ENERGY
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Summary:We have designed a novel 1,8-naphthalimide derivative with an open space for an anion. Computational calculation has predicted that the space could trap various anion species and photo-induced charge transfer depending on the anion's electrophilic properties. Indeed, the fluorescence behaviour of the 1,8-naphthalimide derivative complexes with each anion is consistent with the computational prediction.
Bibliography:KAKEN
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
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ISSN:1359-7345
1364-548X
DOI:10.1039/c5cc01709b