Low-Temperature Rheological Properties and Microscopic Characterization of Asphalt Rubbers Containing Heterogeneous Crumb Rubbers

• Published in: Materials Vol. 13; no. 18; p. 4120
• Main Authors: Chang, Mingfeng, Zhang, Yixing, Pei, Jianzhong, Zhang, Jiupeng, Wang, Min, Ha, Fugui
• Format: Journal Article
• Language: English
• Published: MDPI 16.09.2020; MDPI AG
• Subjects: asphalt rubber; heterogeneous crumb rubbers; linear viscoelastic material functions; microscopic characterization; rheological property
• ISSN: 1996-1944; 1996-1944
• DOI: 10.3390/ma13184120

Asphalt rubbers mixed with untreated and plasticized crumb rubbers and a compounding coupling agent were investigated in this study. The low-temperature rheological properties of asphalt rubbers at different aging levels were tested using a dynamic shear rheometer (DSR). An interconversion between linear viscoelastic material functions was used to obtain converted evaluation indexes for the asphalt rubbers at low temperatures. Lastly, the physicochemical characteristics and the microscopic morphology of the asphalt rubbers were evaluated using Fourier transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM), respectively. In conclusion, the storage moduli of the asphalt rubbers containing heterogeneous crumb rubbers increased with the plasticized crumb rubber content and the aging level. The converted relaxation moduli were consistent with the change trend of the storage moduli, and the relaxation rate decreased as the plasticized crumb rubber content and the aging level increased. The process of mixing the base asphalt with crumb and plasticized crumb rubbers was physical blending, and the effect of aging on the absorption peak change of asphalt rubber with plasticized crumb rubbers was less than that of asphalt rubber with ordinary crumb rubbers. Aging deteriorated the blending between the crumb rubber and the base asphalt, and a distinct interface appeared between the crumb rubber and the base asphalt. The particle cores of the plasticized crumb rubber in the asphalt rubber were difficult to maintain. Furthermore, as the plasticized crumb rubber content increased, more fine particles stripped off the plasticized crumb rubber after aging.