Structures of Dinuclear Copper(II) Complexes Bridged by One Oximato, One Methoxo and One Perchlorato Ligand, and One Oximato and Two Acetato Ligands

The cation of [Cu(L1)(OMe)(ClO4)Cu(bpy)] ClO4 (1) consists of two coppers triply bridged by an oximato, a methoxo, and a perchlorato ligand, where L1 is 3-[2-(2-pyridyl)ethyl]amino-2-butanone oxime. The geometry around each copper is distorted square-pyramidal. The cation of [Cu(L1)(OAc)2Cu(bpy)]ClO...

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Published inBulletin of the Chemical Society of Japan Vol. 74; no. 12; pp. 2375 - 2376
Main Authors Sakamoto, Sachiyo, Yatani, Akihiro, Kimura, Katsusi, Fujii, Mie, Nakao, Yasuo, Kashino, Setsuo, Kinoshita, Masashi, Mori, Wasuke
Format Journal Article
LanguageEnglish
Published Tokyo The Chemical Society of Japan 01.12.2001
Chemical Society of Japan
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Summary:The cation of [Cu(L1)(OMe)(ClO4)Cu(bpy)] ClO4 (1) consists of two coppers triply bridged by an oximato, a methoxo, and a perchlorato ligand, where L1 is 3-[2-(2-pyridyl)ethyl]amino-2-butanone oxime. The geometry around each copper is distorted square-pyramidal. The cation of [Cu(L1)(OAc)2Cu(bpy)]ClO4 (2), consists of two coppers triply bridged by an oximato, an unidentate and a bidentate acetato ligand. The geometry around the coppers is intermediate between a square pyramid and a trigonal bipyramid.
ISSN:0009-2673
1348-0634
DOI:10.1246/bcsj.74.2375