Excellent Electrochemical Performance of Potassium Ion Capacitor Achieved by a High Nitrogen Doped Activated Carbon

• Published in: Journal of the Electrochemical Society Vol. 167; no. 5; pp. 50506 - 50514
• Main Authors: Chen, Zhi, Li, Wenlei, Yang, Jian, Liao, Jiaxuan, Chen, Cheng, Song, Yaochen, Ali Shah, Syed Abbas, Xu, Ziqiang, Wu, Mengqiang
• Format: Journal Article
• Language: English
• Published: IOP Publishing 04.01.2020
• ISSN: 0013-4651; 1945-7111
• DOI: 10.1149/1945-7111/ab6a84

Supercapacitors, due to their unique high-power characteristics, are bound to occupy a place in the field of energy storage. Carbon-based supercapacitor is one of the most promising in all material systems. In this work, N-doped/graphene composite activated carbon (AC) is prepared through a facile method as electrodes for the comparison between an aqueous system and an organic system. The obtained AC shows high surface areas of 1600 m2 g−1 with a high N content of 11.7 wt% and is simultaneously applied to lithium-ions capacitor (LIC), sodium-ions capacitor (NIC) and potassium ion capacitor (KIC). Electrochemical evaluations indicated that the high N-doped activated carbon-based LIC, NIC and KIC possess different performance and energy storage mechanisms. The KIC exhibits the highest energy density of 50 Wh kg−1 at 0.4 A g−1 and the most stable cycle performance of three capacitors. This work reveals differences among the three types of ion capacitors, providing clues for the development of high power-energy and long life ion supercapacitors. Moreover, KIC has better performance than LIC, and the reserve of K is much higher than Li, which makes KIC a better application prospect.