Surface modification of thin film composite membrane by nanoporous titanate nanoparticles for improving combined organic and inorganic antifouling properties

• Published in: Materials Science & Engineering C Vol. 75; pp. 463 - 470
• Main Authors: Emadzadeh, D., Ghanbari, M., Lau, W.J., Rahbari-Sisakht, M., Rana, D., Matsuura, T., Kruczek, B., Ismail, A.F.
• Format: Journal Article
• Language: English
• Published: Netherlands Elsevier B.V 01.06.2017; Elsevier BV
• Subjects: Antifouling; Antifouling substances; Brackish water; Chemical properties; Composite membrane; Contact angle; Contact potentials; Fluctuations; Flux; Fouling; Materials science; Membranes; Membranes, Artificial; Mitigation; Nanocomposites; Nanocomposites - chemistry; Nanoparticles; Nylons - chemistry; Organic and inorganic antifouling; Porosity; Seawater; Synthesis; Thin films; Titanate nanoporous; Titanium - chemistry; Water treatment; X ray photoelectron spectroscopy; Zeta potential; Organic and inorganic antifouling; Water treatment; Titanate nanoporous; Composite membrane
• ISSN: 0928-4931; 1873-0191
• DOI: 10.1016/j.msec.2017.02.079

In this study, nanoporous titanate (NT) nanoparticle synthesized by the solvothermal method was used to modify polyamide layer of thin film composite membranes with the aim of improving membrane resistances against organic and inorganic fouling. Thin film nanocomposite membranes (NMs) were synthesized by adding mNTs (modified nanoparticles) into polyamide selective layer followed by characterization using different analytical instruments. The results of XPS and XRD confirmed the presence of mNTs in the polyamide layer of NMs, while FESEM, AFM, zeta potential and contact angle measurement further supported the changes in physical and chemical properties of the membrane surface upon mNTs incorporation. Results of fouling showed that NM1 (the membrane incorporated with 0.01w/v% mNTs) always demonstrated lower degree of flux decline compared to the control membrane when membranes were tested with organic, inorganic and multicomponent synthesized water, brackish water or seawater. Besides showing greater antifouling resistance, the NM also displayed significantly higher water flux compared to the control M membrane. The findings of this work confirmed the positive impact of mNTs in improving the properties of NM with respect to fouling mitigation and flux improvement. [Display omitted] •AAPTS-modified nanoporous titanate with unique characteristics was synthesized.•This nanoparticle showed positive impact to overcome trade-off effect of membrane permeability and rejection.•Membrane loaded with mNT exhibited improved anti organic/inorganic fouling.