Direct Allylic Functionalization Through Pd-Catalyzed C-H Activation

After a brief introduction emphasizing the synthetic relevance of the allylic C–H activation step, evoking the first pioneering stoichiometric studies that sowed the “seeds” of this subject, and analyzing similarities and differences between a “classical” and a “direct” Pd‐catalyzed allylation proce...

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Published inEuropean journal of organic chemistry Vol. 2014; no. 27; pp. 5863 - 5883
Main Authors Liron, Frédéric, Oble, Julie, Lorion, Mélanie M., Poli, Giovanni
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 01.09.2014
WILEY‐VCH Verlag
Wiley Subscription Services, Inc
Subjects
Allylation
C-H activation
Homogeneous catalysis
Palladium
Reaction mechanisms
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Summary:After a brief introduction emphasizing the synthetic relevance of the allylic C–H activation step, evoking the first pioneering stoichiometric studies that sowed the “seeds” of this subject, and analyzing similarities and differences between a “classical” and a “direct” Pd‐catalyzed allylation process, this review outlines some selected examples of palladium‐catalyzed direct allylic functionalization. This old reaction, ignored for many years, is now living a new and exciting era. This review outlines some selected examples and present challenges relating to palladium‐catalyzed direct allylic functionalization. This old reaction, ignored for many years, is enjoying a new age.
Bibliography:Dedicated to Professor Sandro Cacchi on the occasion of his 70th birthday
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ArticleID:EJOC201402049
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ISSN:1434-193X
1099-0690
DOI:10.1002/ejoc.201402049