Palladium-Catalyzed Carbonylative Synthesis of Aryl Formates under Mild Conditions

Aryl formates have been extensively applied as CO sources in CO‐free carbonylation reactions. However, there are no catalytic synthetic procedures for their preparation. In this manuscript, we developed a convenient palladium‐catalyzed procedure for the synthesis of aryl formates. Good yields were a...

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Published inChemCatChem Vol. 8; no. 10; pp. 1788 - 1791
Main Authors Jiang, Li-Bing, Li, Rui, Li, Hao-Peng, Qi, Xinxin, Wu, Xiao-Feng
Format Journal Article
LanguageEnglish
Published Weinheim Blackwell Publishing Ltd 20.05.2016
Wiley Subscription Services, Inc
Subjects
carbonylation
CO free
coupling reactions
formates
palladium
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Abstract Aryl formates have been extensively applied as CO sources in CO‐free carbonylation reactions. However, there are no catalytic synthetic procedures for their preparation. In this manuscript, we developed a convenient palladium‐catalyzed procedure for the synthesis of aryl formates. Good yields were achieved under mild reaction conditions with formic acid as the formyl source. A formyl meeting: A convenient palladium‐catalyzed carbonylation procedure for the synthesis of aryl formates is developed. Good yields are achieved under mild reaction conditions with formic acid as the formyl source.
AbstractList Abstract Aryl formates have been extensively applied as CO sources in CO‐free carbonylation reactions. However, there are no catalytic synthetic procedures for their preparation. In this manuscript, we developed a convenient palladium‐catalyzed procedure for the synthesis of aryl formates. Good yields were achieved under mild reaction conditions with formic acid as the formyl source.
Aryl formates have been extensively applied as CO sources in CO‐free carbonylation reactions. However, there are no catalytic synthetic procedures for their preparation. In this manuscript, we developed a convenient palladium‐catalyzed procedure for the synthesis of aryl formates. Good yields were achieved under mild reaction conditions with formic acid as the formyl source. A formyl meeting: A convenient palladium‐catalyzed carbonylation procedure for the synthesis of aryl formates is developed. Good yields are achieved under mild reaction conditions with formic acid as the formyl source.
Aryl formates have been extensively applied as CO sources in CO-free carbonylation reactions. However, there are no catalytic synthetic procedures for their preparation. In this manuscript, we developed a convenient palladium-catalyzed procedure for the synthesis of aryl formates. Good yields were achieved under mild reaction conditions with formic acid as the formyl source.
Author Jiang, Li-Bing
Qi, Xinxin
Li, Hao-Peng
Wu, Xiao-Feng
Li, Rui
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  organization: Department of Chemistry, Zhejiang Sci-Tech University, Xiasha Campus, 310018, Hangzhou, P.R. China
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Snippet Aryl formates have been extensively applied as CO sources in CO‐free carbonylation reactions. However, there are no catalytic synthetic procedures for their...
Abstract Aryl formates have been extensively applied as CO sources in CO‐free carbonylation reactions. However, there are no catalytic synthetic procedures for...
Aryl formates have been extensively applied as CO sources in CO-free carbonylation reactions. However, there are no catalytic synthetic procedures for their...
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SubjectTerms carbonylation
CO free
coupling reactions
formates
palladium
Title Palladium-Catalyzed Carbonylative Synthesis of Aryl Formates under Mild Conditions
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