Palladium-Catalyzed Carbonylative Synthesis of Aryl Formates under Mild Conditions

Aryl formates have been extensively applied as CO sources in CO‐free carbonylation reactions. However, there are no catalytic synthetic procedures for their preparation. In this manuscript, we developed a convenient palladium‐catalyzed procedure for the synthesis of aryl formates. Good yields were a...

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Bibliographic Details
Published inChemCatChem Vol. 8; no. 10; pp. 1788 - 1791
Main Authors Jiang, Li-Bing, Li, Rui, Li, Hao-Peng, Qi, Xinxin, Wu, Xiao-Feng
Format Journal Article
LanguageEnglish
Published Weinheim Blackwell Publishing Ltd 20.05.2016
Wiley Subscription Services, Inc
Subjects
carbonylation
CO free
coupling reactions
formates
palladium
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Summary:Aryl formates have been extensively applied as CO sources in CO‐free carbonylation reactions. However, there are no catalytic synthetic procedures for their preparation. In this manuscript, we developed a convenient palladium‐catalyzed procedure for the synthesis of aryl formates. Good yields were achieved under mild reaction conditions with formic acid as the formyl source. A formyl meeting: A convenient palladium‐catalyzed carbonylation procedure for the synthesis of aryl formates is developed. Good yields are achieved under mild reaction conditions with formic acid as the formyl source.
Bibliography:ArticleID:CCTC201600165
istex:B42C151777EC0EB8889A3194F563F2EEE85B9791
National Natural Science Foundation of China (NSFC) - No. 21472174
ark:/67375/WNG-PQ9GLK0M-X
Zhejiang Natural Science Fund for Distinguished Young Scholars - No. LR16B020002
ISSN:1867-3880
1867-3899
DOI:10.1002/cctc.201600165