An anisaldehyde sodium bisulfite derivative: poly[[μ4-(hydroxy)(4-methoxyphenyl)methanesulfonato]sodium]

The title complex, [Na(C8H9O5S)]n, is polymeric and consists of broad layers parallel to (100) made up of an inner hydrophilic core of Na+ cations and polar SO3C(OH)– groups, padded on both sides by two hydrophobic layers of pendant methoxyphenyl groups. The Na+ cations in the inner core are six‐coo...

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Bibliographic Details
Published inActa crystallographica. Section C, Crystal structure communications Vol. 69; no. 1; pp. 52 - 55
Main Authors Díaz de Vivar, M. Enriqueta, Baggio, Sergio, Baggio, Ricardo
Format Journal Article
LanguageEnglish
Published 5 Abbey Square, Chester, Cheshire CH1 2HU, England International Union of Crystallography 01.01.2013
Subjects
Cations
Crystal structure
Derivatives
Distortion
Hydrogen bonds
Ligands
Sodium
Two dimensional
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Summary:The title complex, [Na(C8H9O5S)]n, is polymeric and consists of broad layers parallel to (100) made up of an inner hydrophilic core of Na+ cations and polar SO3C(OH)– groups, padded on both sides by two hydrophobic layers of pendant methoxyphenyl groups. The Na+ cations in the inner core are six‐coordinated into highly distorted NaO6 octahedra by four symmetry‐related (hydroxy)(4‐methoxyphenyl)methanesulfonate anions, leading to a tightly woven two‐dimensional structure. While there are some hydrogen bonds providing interplanar cohesion, interactions between adjacent layers are weak hydrophobic ones. The present compound appears to be the first reported structure containing the (hydroxy)(4‐methoxyphenyl)methanesulfonate ligand.
Bibliography:ark:/67375/WNG-4J5F510K-S
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ISSN:0108-2701
1600-5759
DOI:10.1107/S0108270112047774